Four new methods using titrimetry and spectrophotometry are described for the rapid determination of amoxycillin in bulk drug and dosage forms. In direct titrimetry (Method A), the drug is titrated with bromate–bromide mixture in acid medium using methyl orange indicator. Back titrimetry (Method B) entails adding a known excess amount of bromatebromide mixture to the drug solution in acid mediu...

In this study, oxidation of some 3,5-diacyl or 3,5-diester 1,4-dihydropyridines to corresponding pyridine derivatives using sodium bromate in the presence of NH4Cl, NaHSO4 and Bu4NHSO4 under thermal conditions has been investigated. The yield and structure of formed products is similar under all conditions; however, the reaction is accelerated in the presence of Bu4NHSO4 and NaHSO4. In addition...

The presence of bromine as a trace-element in calcium carbonate speleothems constitutes useful proxy past volcanic activity, thus helping to provide input parameters for climate model simulations and risk assessment. However, the chemical nature bromine-containing impurities phases forming is not understood, which limits interpretation experimental measurements on speleothems. We present here c...

a kinetic spectrophotometric method for rapid measurement of thiocyanate in serum, urine and sewage water with no need for removed of interfering substances in described. the method is based on the inhibitory effect of thiocyanate on the oxidation of pyrogallol red by bromated and nitrite which is monitored at 467 nm. the variables affecting the rate of the reaction were investigated and the op...

Providing safe tap water while limiting the occurrence of disinfection by-products (DBPs) is probably one most challenging aspects environmental chemical engineering within urban cycle. In present work, an investigation about this challenge for real conditions a full-scale drinking treatment plant has been carried out. Five different and well-known technologies (four aeration procedures, coagul...

the structure of the nonaaquayttrium (iii) bromate, [y(h2o)9](bro3)3, at low temperature (100 k) has been studied by means of single-crystal x-ray diffraction. crystallography shows a hexagonal unit cell, space group p63/mmc (no. 194) with z = 2, a = b = 11.7104(11) å, c = 6.6259(5) å and v = 786.90(12) å3 at 100 k. the hydrated trivalent yttrium(iii) ion forms a tricapped trigonal prism, in wh...