The CH(3)I A-state-assisted photofragmentation of the (CH(3)I)(2) van der Waals dimer at 248 nm and nearby wavelengths has been revisited experimentally using the time-of-flight mass spectrometry with supersonic and effusive molecular beams and the "velocity map imaging" technique. The processes underlying the appearance of two main (CH(3)I)(2) cluster-specific features in the mass spectra, nam...

The catalytic activity and selectivity of platinum metals can be altered dramatically and reversibly by interfacing the metal with a solid electrolyte which supplies ions onto the catalyst sugace under the influence of an external potential. The induced change in catalytic rate is orders of magnitude higher than the rate of ion supply. This new effect has revealed a surprisingly simple exponent...

Chemical precipitation is a widely used, proven technology for the removal of metals and other inorganics, suspended solids, fats, oils, greases, and some other organic substances (including organophosphates) from wastewater. Generally speaking, precipitation is a method of causing contaminants that are either dissolved or suspended in solution to settle out of solution as a solid precipitate, ...

In an effort to expand the therapeutic range of platinum anticancer agents, several new approaches to platinum-based therapy, including nanodelivery, are under active investigation. To better understand the effect of ligand lipophilicity on the encapsulation of Pt(IV) prodrugs within polymer nanoparticles, the series of compounds cis,cis,trans-[Pt(NH3)2Cl2L2] was prepared, where L = acetate, pr...

Use of biomass as alternatives to petrochemicals has attracted a broad range of scientific and industrial interests. We propose here a novel environmentally-friendly recycle system for precious metal ions such as gold and platinum ions using protein-rich biomass. My keynote lecture is composed of three pieces; (1) selective adsorption of precious metal ions onto proteins, (2) the mechanism stud...

A new potentially hexadentate P(2)N(4) ligand has been prepared and its coordination chemistry to Pd(II) and Pt(II) investigated. The ligand bonds in a chelating fashion via the diphosphine backbone to PdCl(2) and PtCl(2) while the appended pyridyl groups remain non-bonding. Abstraction of the chloride ions from the platinum complex results in fluxional exchange of the pyridyl groups in solutio...

Plant viruses are considered as nanobuilding blocks that can be used as synthons or templates for novel materials. Cowpea mosaic virus (CPMV) particles have been shown to template the fabrication of metallic nanoparticles by an electroless deposition metallization process. Palladium ions were electrostatically bound to the virus capsid and, when reduced, acted as nucleation sites for the subseq...