The excited states of UV-B absorbers, ethylhexyl triazone (EHT) and diethylhexylbutamido triazone (DBT), have been studied through measurements of UV absorption, fluorescence, phosphorescence, triplet-triplet absorption and electron paramagnetic resonance spectra in ethanol. The energy levels of the lowest excited singlet (S1) and triplet (T1) states and quantum yields of fluorescence and phosp...

A laser diagnostic technique useful for qualitatively locating and describing regions of vapor and liquid structures of a pressure atomized fuel spray is examined. While Mie scattering is sensitive to the liquid phase within a spray, planar laser-induced fluorescence is sensitive to both the liquid and vapor phases. Hence, a comparison of images utilizing these two techniques could be used to q...

Mik EG, Johannes T, Ince C. Monitoring of renal venous PO2 and kidney oxygen consumption in rats by a near-infrared phosphorescence lifetime technique. Am J Physiol Renal Physiol 294: F676–F681, 2008. First published January 9, 2008; doi:10.1152/ajprenal.00569.2007.— Renal oxygen consumption (V̇O2,ren) is an important parameter that has been shown to be influenced by various pathophysiological c...

A new phosphorescent zinc sensor (ZIrF) was constructed, based on an Ir(III) complex bearing two 2-(2,4-difluorophenyl)pyridine (dfppy) cyclometalating ligands and a neutral 1,10-phenanthroline (phen) ligand. A zinc-specific di(2-picolyl)amine (DPA) receptor was introduced at the 4-position of the phen ligand via a methylene linker. The cationic Ir(III) complex exhibited dual phosphorescence ba...

A lifetime-based molecular tagging thermometry technique was developed for achieving simultaneous measurements of droplet size and transient temperature distribution within a small water droplet over a solid surface. For molecular tagging thermometry measurements, a pulsed laser is used to tag phosphorescent 1-BrNp M -CD ROH molecules premixed within a small water droplet. Long-lived laser-indu...

High-resolution fluorescence, phosphorescence, as well as related excitation spectra, and, in particular, the emission decay behavior of solid [Bu4N]4[Pt2(μ-P2O5(BF2)2)4], abbreviated Pt(pop-BF2), have been investigated over a wide temperature range, 1.3-310 K. We focus on the lowest excited states that result from dσ*pσ (5dz(2)-6pz) excitations, i.e., the singlet state S1 (of (1)A2u symmetry i...

This study investigates both decreases and increases of aromatic carbonyl phosphorescence in excited nitrogen, i.e., in a gas-chromatographic device called the aroyl luminescence detector (ALD). The ALD responds, with nigh specificity, to subpicogram amounts of strongly phosphorescing aroyls. Aroyl response may, however, be quenched by coeluting peaks or gaseous impurities. This deleterious eff...

The fluorescence and phosphorescence of 2,2'-bis(5-phenyl-1,3,4-oxadiazol-2-yl)biphenyl shows good spectral matching with the absorption spectra of the MLCT1 and MLCT3 transitions of Ir(ppy)3. The red-shift of the 0-0 band in the phosphorescence at 77 K is due to the intramolecular pi-pi interactions between the oxadiazole side chains. Maximum brightness of 43,000 cd/m2 with an efficiency of 26...

The strong light emission of organic luminogens in the aggregated state is essential to their applications as optoelectronic materials with good performance. In this review, with respect to the aggregation-induced emission and room-temperature phosphorescence luminogens, the important role of molecular packing modes is highlighted. As demonstrated in the selected examples, the molecular packing...

The control of the emission properties of synthetic organic molecules through molecular design has led to the development of high-performance optoelectronic devices with tunable emission colours, high quantum efficiencies and efficient energy/charge transfer processes. However, the task of generating excited states with long lifetimes has been met with limited success, owing to the ultrafast de...