نتایج جستجو برای: palladium

تعداد نتایج: 12345  

Journal: :Contact dermatitis 2014
Maria Pesonen Liisa Airaksinen Risto Voutilainen Riitta Riekki Soile Jungewelter Katri Suuronen

A 50-year-old previously healthy non-smoking laboratory technician, who had worked in catalyst research for 26 years, presented with recurrent urticaria on the hands and the face, and watery rhinitis associated with handling palladium salts at work. When exposed to fine dusts of dried and powdered mixtures containing the palladium nitrate salts Pd(NH3)4(NO3)2 and Pd(NO3)2, she immediately devel...

Journal: :Dalton transactions 2014
Shrikant M Khake Vineeta Soni Rajesh G Gonnade Benudhar Punji

Well-defined and efficient POCN-ligated palladium complexes have been developed for the direct C-H bond arylation of azoles with aryl iodides. The phosphinite-amine pincer ligands 1-(R2PO)-C6H4-3-(CH2N(i)Pr2) [(R2)POCN(iPr2)-H; R = (i)Pr (), R = (t)Bu ()] and corresponding palladium complexes {2-(R2PO)-C6H3-6-(CH2N(i)Pr2)}PdCl [((R2)POCN(iPr2))PdCl; R = (i)Pr (), R = (t)Bu ()] were synthesized ...

Journal: :Physical chemistry chemical physics : PCCP 2015
Eun Hee Jeon Sena Yang Sung Ho Kang Sehun Kim Hangil Lee

We report about the mechanistic studies of the reaction between a newly synthesized (S)-2-((R)-3H-dinaphtho[2,1-c:1',2'-e]azepin-4(5H)-yl)-2-phenylethanol based on the binaphthyl skeleton and (E)-2-methyl-5-phenylpent-2-enoic acid for the asymmetric hydrogenation of α,β-unsaturated acids with heterogeneous palladium catalysts. The specific interactions between the chiral ligand and reactant wer...

Journal: :Chemical communications 2012
Shengqing Ye Jie Wu

Aryl N-aminosulfonamides could be easily produced via a palladium-catalyzed coupling of aryl halides, potassium metabisulfite, and hydrazines. Potassium metabisulfite is an excellent equivalent of sulfur dioxide in the reaction of palladium-catalyzed aminosulfonylation.

2013
Vlad Pascanu Qingxia Yao Antonio Bermejo Gómez Mikaela Gustafsson Yifeng Yun Wei Wan Louise Samain Xiaodong Zou Belén Martín-Matute

Palladium nanoparticles have been immobilized into an amino-functionalized metal-organic framework (MOF), MIL-101Cr-NH2, to form Pd@MIL-101Cr-NH2. Four materials with different loadings of palladium have been prepared (denoted as 4-, 8-, 12-, and 16 wt%Pd@MIL-101Cr-NH2). The effects of catalyst loading and the size and distribution of the Pd nanoparticles on the catalytic performance have been ...

Journal: :The journal of physical chemistry. B 2006
Abderrafik Nemamcha Jean-Luc Rehspringer Djameledine Khatmi

The sonochemical synthesis of stable palladium nanoparticles has been achieved by ultrasonic irradiation of palladium(II) nitrate solution. The starting solutions were prepared by the addition of different concentrations of palladium(II) nitrate in ethylene glycol and poly(vinylpyrrolidone) (PVP). The resulting mixtures were irradiated with ultrasonic 50 kHz waves in a glass vessel for 180 min....

Journal: :Chemical communications 2010
Mithun Santra Sung-Kyun Ko Injae Shin Kyo Han Ahn

A fluorescein-based fluorescent probe displays fluorescence enhancement for palladium species in the typical oxidation states of 0, +2 and +4 and is applied to monitor accumulated palladium in living organisms.

Journal: :Chemical communications 2009
Shengqing Ye Ke Gao Haibo Zhou Xiaodi Yang Jie Wu

Palladium-catalyzed tandem reactions of 2-alkenylphenyl-acetylenes with CuCl2 or CuBr2 afforded 3-chloro- or 3-bromo-1-methyleneindenes in good yields; these compounds could be further elaborated via palladium-catalyzed coupling reactions.

Razieh Zakerian Soleiman Bahar,

In this study, we combined Ionic Liquid-based Dispersive Liquid Liquid Micro Extraction (IL-DLLME) with FAAS for determining the palladium in different real samples at the trace level. 1-hexyl-3-methylimidazolium hexafluorophosphate [Hmim][PF6] ionic liquid and 1-(2-pyridylazo) 2-naphthol (PAN), were chosen as the extraction solvent and the chelating agent, respectively. The hydr...

Journal: :Molecules 2017
Shengjie Wu Mingjin Xie Qin Zhang Lijiang Zhong Muhan Chen Zhangjie Huang

Conventional separation methods are not suitable for recovering palladium present in low concentrations in ore leaching solutions. In this study, a novel isopentyl sulfide (S201)-impregnated α-MnO₂ nanorod adsorbent (BISIN) was prepared, characterized, and applied for the selective adsorption and separation of palladium from the leaching liquor of ores. Batch studies were carried out, and the m...

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