The 5-day sodium carbonate-ammonium nitrate extraction assay (5-day method) has been recognized by the American Association of Plant Food Control Officials as a validated test method to identify fertilizers or beneficial substances that provide plant-available silicon (Si). The test method used the molybdenum blue colorimetric assay to quantify percentage Si; however, laboratories may use induc...

A METals In Situ analyzer (METIS) has been used to determine dissolved manganese (II) concentrations in the subhalocline waters of the Gotland Deep (central Baltic Sea). High-resolution in situ measurements of total dissolved Mn were obtained in near real-time by spectrophotometry using 1-(2-pyridylazo)-2-naphthol (PAN). PAN is a complexing agent of dissolved Mn and forms a wine-red complex wit...

Inorganic compounds in biomass, often referred to as ash, are known to be problematic in the thermochemical conversion of biomass to bio-oil or syngas and, ultimately, hydrocarbon fuels because they negatively influence reaction pathways, contribute to fouling and corrosion, poison catalysts, and impact waste streams. The most common ash-analysis methods, such as inductively coupled plasma-opti...

The aim of the study was to compare concentrations risk elements (As, Cu, Mn, Ni, Pb, Zn) in alluvial soil, which were measured by a portable X-ray fluorescence analyser (pXRF) situ (FIELD) and laboratory (LABORATORY). Subsequently, regression equations developed for individual through method construction model, results pXRF with classical analysis (ICP-OES). accuracy measurement, expressed coe...

Atomic hydrogen (H) was introduced into steel (AISI 1018 mild steel) by controlled cathodic pre-charging. The resultant steel sample, comprising about 1 ppmw diffusible H, and a reference uncharged sample, were studied using atomic emission spectroelectrochemistry (AESEC). AESEC involved potentiodynamic polarisation in a flowing non-passivating electrolyte (0.6 M NaCl, pH 1.95) with real time r...

Chandrakanthi Chooranam, a siddha sastric herbomineral formulation comprises of 25 ingredients. Literature review evidenced no standardization work so far. Authors aims to investigate various analytical standardization parameters such as physicochemical standards, preliminary phytochemical analysis, Thin Layer Chromatography (TLC) photo documentation, High Performance Thin Layer Chromatography ...

Baixas concentrações dos catorze elementos de ocorrência natural da série lantanídeos foram diretamente determinadas por espectrometria de emissão óptica com plasma indutivamente acoplado (ICP OES). Avaliaram-se interferências espectrais e linhas espectrais mais adequadas foram selecionadas. Os desempenhos da nebulização pneumática e ultra-sônica foram comparados com respeito aos limites de det...

A validation study in order to evaluate the efficiency of the inductively coupled plasma optical emission spectrometry (ICP-OES) in the analysis of minor elements (Manganese, Chromium, Copper, Iron and Titanium) in aluminium alloys was carried out. Aluminium casting samples were obtained from addition to aluminium baths of compressed powder compacts of each alloying element and aluminium (minit...

The Vista instrument has a number of distinct advantages over similar ICP-OES systems. Firstly, the VistaChip is the only single Charge Coupled Device (CCD) that allows full coverage of the spectrum from 165-785nm, with a pixel processing speed of 1 MHz and exceptional anti-blooming properties. These features allow both trace level analytes and major analytes to be determined in the same measur...

Foram comparados vários procedimentos de preparo de amostras, isto é, decomposição total de uma mistura HNO3/H2O2 em placa de aquecimento, decomposição parcial por meio de solubilização em aqua regia e diluição com solução de HNO3 de baixa concentração, para determinação do conteúdo total de Ba, Ca, Cd, Cr, Cu, Fe, Mg, Mn, Ni, P, Pb, Sr e Zn em bebidas energéticas utilizando espectrometria de e...