We report here that photoinitiated electron flow involving a metal-substituted (M = Mg, Zn) myoglobin (Mb) and its physiological partner protein, cytochrome b5 (cyt b5) can be "symmetrized": the [Mb:cyt b5] complex stabilized by three D/E → K mutations on Mb (D44K/D60K/E85K, denoted MMb) exhibits both oxidative and reductive ET quenching of both the singlet and triplet photoexcited MMb states, ...

We study the quenching behavior for a semilinear heat equation arising in models of micro-electro mechanical systems (MEMS). The problem involves a source term with a spatially dependent potential, given by the dielectric permittivity profile, and quenching corresponds to a touchdown phenomenon. It is well known that quenching does occur. We prove that touchdown cannot occur at zero points of t...

The excited-state quenching of zinc meso-tetrakis(4-sulfonatophenyl)porphyrin (ZnTPPS) by halide ions has been studied in water and various aqueous micellar solutions using both steady-state and time-resolved fluorescence techniques. The quenching efficiencies of the S(1) state of ZnTPPS ([small tau][approximate] 1.93 ns) by halide ions in homogeneous aqueous solution increase in the order Cl(-...

In this study, some parameters such as quenching and boiling curves of a stainless steel cylindrical rod 80 mm long and having a diameter of 15 mm were experimentally obtained in saturate pure water and two nanofluids (SiO2 and TiO2) with 0.01 wt%. The cylinder was vertically lowered into the pool of saturated water and its temporal center temperature was measured by a the...

The innovative hot stamping press of quenchable steel mainly includes two stages: hot forming of blank at elevated temperature and quenching of hot stamped part in closed water-cooled tools. Crucial stage in hot stamping process is quenching of hot formed part in water-cooled tool to achieve final high ultimate tensile strength. In quenching stage, cooling rate of hot stamped part has a signifi...

In this study, three-dimensional finite-element (FE) analyses were carried out to predict the volume fractions of various phases generated during the quenching process of plain-carbon steel and the temperature history, considering the latent heat generated due to phase transformation. Diffusional phase transformation for a nonisothermal process was described by discretizing the cooling curve in...

We consider thermal fluid structure interaction to model industrial gas quenching in steel forging, where hot steel is cooled using cold high pressured gas. This allows to define properties of the finished steel part, as for example yield strength, locally at low cost and without environmental problems. For the numerical simulation, a partitioned approach via a Dirichlet-Neumann coupling and a ...