We consider the excursions, i.e., the intervals between consecutive zeros, of stochastic processes that arise in a variety of nonequilibrium systems and study the temporal growth of the longest one l_{max}(t) up to time t. For smooth processes, we find a universal linear growth l_{max}(t) approximately Q_{infinity}t with a model dependent amplitude Q_{infinity}. In contrast, for nonsmooth proce...

Using field-theoretic techniques, we develop a molecularly based dipolar self-consistent-field theory (DSCFT) for charge solvation in pure solvents under equilibrium and nonequilibrium conditions and apply it to the reorganization energy of electron transfer reactions. The DSCFT uses a set of molecular parameters, such as the solvent molecule's permanent dipole moment and polarizability, thus a...

A new method is offered to simulate heat transfer processes in nonequilibrium viscous shock layers near the catalytic body surface at hypcrsonic wind tunnel and free natural flight conditions. The method is based on computations of nonequilibrium parameters in thin viscous sbock layers, and on an analogy with flows that arise behind normal shock waves. The obtained simplified relationships betw...

The effects of solvent on molecular processes such as excited state relaxation and photochemical reaction often occurs in a nonequilibrium regime. Dynamic processes such as these can be simulated using excited statemolecular dynamics. In this work, we describe methods of simulating nonequilibrium solvent effects in excited statemolecular dynamics using linear-response time-dependent density fun...

We present a Brownian inchworm model of a self-propelled elastic dimer in the absence of an external potential. Nonequilibrium noise together with a stretch-dependent damping form the propulsion mechanism. Our model connects three key nonequilibrium features -- position-velocity correlations, a nonzero mean internal force, and a drift velocity. Our analytical results, including striking current...

We resolve the structure of a c(2x2) reconstruction of the rutile TiO2 (100) surface using a combination of transmission electron diffraction, direct methods analysis, and density functional theory. The surface structure contains an ordered array of subsurface oxygen vacancies and is in local thermodynamic equilibrium with bulk TiO2, but not the with oxygen gas-phase environment. The transition...

Nonequilibrium periodic nanostructures such as nanoscale ripples, mounds and rhomboidal pyramids formed on Rh(110) are particularly interesting as candidate model systems with enhanced catalytic reactivity, since they are endowed with steep facets running along nonequilibrium low-symmetry directions, exposing a high density of undercoordinated atoms. In this review we report on the formation of...

We demonstrate that icosahedral Al-Pd-Mn quasicrystals can have nonicosahedrally ordered thermodynamic equilibrium overlayers. The formation of orthorhombic or decagonal equilibrium surface structures is determined by the phase equilibrium of the ternary alloy at given composition and temperature as well as by the surface acting as nucleation site. Nonequilibrium steady-state orthorhombic and h...

[1] Diurnal restratification of the ocean surface boundary layer (OSBL) represents a competition between mixing of the OSBL and solar heating. Langmuir turbulence (LT) is a mixing process in the OSBL, driven by wind and surface waves, that transfers momentum, heat, and mass. Observations in nonequilibrium swell conditions reveal that the OSBL does not restratify despite low winds and strong sol...