the nanostructured anatase tio2 with high thermal stability was prepared by polymeric sol-gel method without any additives. the particle size distribution of polymeric titania sol was determined by dynamic light scattering (dls). then properties of obtained titania were investigated by tg-dta, xrd, fesem and tem. also, the decolorization capability of resultant anatase was evaluated using methy...

There is intense interest in developing new novel nanostructured photoanodes for water splitting. It is therefore important that methods to analyze the effect of nanostructuring on water splitting yields are developed in order to rationalize the relative merits of this approach for different materials. In this study the dependence of charge separation efficiency (η(sep)) on potential during pho...

An oxygen gas microsensor based on nanostructured sol-gel TiO2 thin films with a buried Pd layer was developed on a silicon substrate. The nanostructured titania thin films for O2 sensors were prepared by the sol-gel process and became anatase after heat treatment. A sandwich TiO2 square board with an area of 350 μm × 350 μm was defined by both wet etching and dry etching processes and the wet ...

An interatomic potential model has been developed for molecular-dynamics simulations of TiO2 ~rutile! based on the formalism of Streitz and Mintmire @J. Adhes. Sci. Technol. 8, 853 ~1994!#, in which atomic charges vary dynamically according to the generalized electronegativity equalization principle. The present model potential reproduces the vibrational density of states, the pressure-dependen...

The polymer electrolyte fuel cell (PEFC) is an attractive power generation method from the perspective of environmental protection. Carbon is usually used as a catalyst support in PEFC, but it is oxidized under high electrical potential conditions. Ti4O7 is expected as a new catalyst support because of its high electrical conductivity and chemical resistivity. Though Ti4O7 as a catalyst support...

A thorough characterization of nanostructured materials under application-relevant conditions is a prerequisite for elucidating the interplay between their physicochemical nature and their functional properties in practical applications. Here, we use a spectroelectrochemical approach to study the population of electronic states in different types of nanostructured anatase and rutile TiO2 films ...

During air–slip direct chill casting of aluminum alloys, uneven or low air pressure areas at the surface of the porous graphite ring mold, can cause the metal to stick to the graphite ring and produce traces along the billets called vertical drags (VD). To prevent this type of defect, it would be an advantage to decrease the wettability of the graphite ring. It has been shown that nanostructure...

Grazing-incidence small-angle x-ray scattering (GISAXS) is a standard tool for the analysis of surfaces and thin layers containing nanometer-sized structures. In order to obtain a two-dimensional map of their local morphology, we performed GISAXS microtomography on dried drops of colloidal suspensions. In particular, we investigated the self-organization of drying suspensions of TiO2 on polyeth...

The complex mechanisms of the bone cell-surface interactions are yet to be completely understood, and researchers continue to strive to uncover the fully optimized implant material for perfect osseointegration. A particularly fascinating area of research involves the study of nanostructured surfaces, which are believed to enhance osteogenic behavior, possibly due to the mimicry of components of...

Nanostructured Si as the high efficiency photoelectrode material is hard to keep stable in aqueous for water splitting. Capping a passivation layer on the surface of Si is an effective way of protecting from oxidation. However, it is still not clear in the different mechanisms and effects between insulating oxide materials and oxide semiconductor materials as passivation layers. Here, we compar...