Supercritical fluids and ionic liquids offer attractive opportunities for modifying and applying zeolites as adsorbents and catalysts. After a brief introduction to the most important properties of these solvents, examples of zeolite applications in supercritical fluids and ionic liquids from the recent literature are discussed. Particular emphasis is put on the influence of reaction media on t...

In-situ synthesis of a zeolite with encapsulated Pt was conducted to prepare a sulfur-resistant noble metal catalyst based on concepts of shape selectivity and hydrogen spillover. The prepared zeolite was of the sodalite type, in which the pore openings allow H2 to enter the pores but not H2S. Chemisorption with H2/CO was conducted to verify the most of Pt atoms distribution in the cage of Pt/S...

Zeolitic self-enclosed micro-cavities were successfully fabricated. In the process, a zeolite film was grown on silicon wafer followed by pore activation and wet etching. Etchant molecules diffused through the zeolite pores and etched the silicon underneath. Nitric acid and pyridine were used for the feasibility study of chemical storages and releases using the microcavities. The release of nit...

The naphtha catalytic reforming process is evaluated by designing new composite nano-catalysts. Three catalysts were prepared for this process. first catalyst was molybdenum carbide with platinum over HY zeolite (Mo2C.Pt/HY zeolite), the second modified cerium nitrate (Mo2C.Pt/CeY and last bimetallic titanium a content of 1% 0.11% (Pt.Ti/HY zeolite). All tested several tests, mainly X-Ray Diffr...

The gas flow in shale matrix is of great research interests for optimized shale gas extraction. The gas flow in the nano-scale pore may fall in flow regimes such as viscous flow, slip flow and Knudsen diffusion. A 3-dimensional nano-scale pore network model was developed to simulate dynamic gas flow, and to describe the transient properties of flow regimes. The proposed pore network model accou...

Nano-zeolite is an innovative class of materials that received recognition for its potential use in water and tertiary wastewater treatment. These applications include ion-exchange/sorption, photo-degradation, membrane separation. The aim this work to summarize analyze the current knowledge about utilization nano-zeolite these applications, identify gaps field, highlight challenges face wide sc...

This study evaluated the applicability of natural zeolite for the removal of the NH-forms in the enzyme-mediated calcite precipitation technique. The natural zeolite of mordenite was added to prepared grouting solutions composed of urea and urease and mixed thoroughly using a rotation table for the mixing times of 0.5, 1.0, and 2.0 h. Then, the concentrations of evolving NH-forms in the solutio...

The effects of varying the silica source on synthesis of NaX zeolite crystals via conventional hydrothermal method have been investigated. Five different silica sources were selected while other parameters like Al source, reaction and aging time, SiO2/Al2O3 molar ratio and temperature were same. The prepared products were characterized by XRD technique. The results showed that different cry...