The synthesis under MW irradiation without solvent of 19 pyrazoles, of which only 8 were known, is described. They bear C-methyl groups and trityl, diphenylmethyl and benzyl groups at positions 1 and 4 of the pyrazole ring. In the reaction between pyrazole and trityl bromide an unexpected reaction occurred and 4-(9-phenyl-9H-fluoren-9-yl)-1Hpyrazole (7) was isolated.

the key role of chemokine receptor cxcr4 in the maintenance of stemness property of stem cells has been shown recently. the low level laser irradiation (llli) is being used currently in a wide variety of clinical cases as a therapeutic tool for wound healing, relieving pain and destroying tumor cells. the aim of this study was to evaluate the effect of llli mimicking low level laser therapy (ll...

Fe clusters incorporated in a graphene matrix exhibit photo-assisted increase of 110% reverse water gas shift CO 2 hydrogenation under UV-Vis light irradiation at 120 mW cm ?2 .

We have synthesized soluble TiOPc derivatives containing alkoxy groups for use as additives in dye-sensitized solar cells (DSSCs). The DSSC devices containing these TiOPc derivatives exhibited short-circuit current densities of 8.49~10.04 mA/cm(2) and power conversion efficiencies of 2.73~3.62 % under AM 1.5 illumination and 100 mW/cm(2) irradiation.

We have fabricated highly efficient CdS/CdSe quantum dot-sensitized solar cells (QDSSCs) featuring low-cost cobalt sulfide (CoS) counter electrodes. Under 100 mW cm(-2) irradiation, the CdS/CdSe QDSSC featuring a CoS electrode provided an energy conversion efficiency as high as 3.4%.

Presently lignin is used as fuel but recent interests in biomaterials encourage the use of this polymer as a renewable feedstock in manufacturing. The present study was undertaken to explore the potential applicability of microwaves to isolate lignin from agricultural residues. A central composite design (CCD) was used to optimize the processing conditions for the microwave (MW)-assisted extrac...

PURPOSE To investigate whether optimized photoactivated chromophore for keratitis-corneal collagen cross-linking (PACK-CXL) treatment settings allow accelerating treatment while maintaining antibacterial efficacy. METHODS Staphylococcus aureus and Pseudomonas aeruginosa strains were irradiated with ultraviolet-A light of equal fluence but different intensity settings (18 mW/cm² for 5 minutes ...

The potential benefits of microwave irradiation for fructose dehydration into 5 hydroxymethylfurfural (5-HMF) have been quantified over a sulfonated metal–organic framework (MOF), MIL 101(Cr)-SO3H. effects temperature (140–170 °C), batch time (5–300 min), and catalyst-to-substrate ratio (0.1–0.01 g/g) were systematically mapped. After 10 min (MW) at 140 °C in DMSO–acetone reaction medium, pract...

Recent observations of nonthermal, resonant biological responses to weak millimeter microwave irradiation have led us to investigate whether similar influences exist on enzymatic functions in vitro. We chose (i) the reduction of ethanol in the presence of alcohol dehydrogenase and (ii) the cooperative binding of oxygen on hemoglobin. Using an irradiation intensity near 10 mW/cm2 the frequency w...