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Open-framework chalcogenides are potential electrode materials for sodium-ion batteries (SIBs) due to their architectures with fast-ion conductivity. Herein, we report on the successful synthesis of open-framework Cu-Ge-based chalcogenides [Cu8Ge6Se19](C5H12N)6 (CGSe) and the research of their energy storage application as SIB anodes for the first time. As a result, the CGSe anode exhibited goo...
We report measurements of the valence band width in compressed Ge determined from x-ray emission spectra below the Ge K edge. The width of the valence band does not show any pressure dependence in the semiconducting diamond-type structure of Ge below 10 GPa. On the other hand, in the metallic beta-Sn phase above 10 GPa the valence band width increases under compression. Density-functional calcu...
Vortices play a central role in determining the static and dynamic properties of two-dimensional (20) superconductors. Artificially fabricated networks of superconducting islands weakly coupled by Josephson junctions are model systems to study the behavior of vortices. Studies of vortices in Josephson junction arrays generally neglect the magnetic fields induced by currents flowing in the array...
Using Fourier transform infrared-attenuated total reflectance spectroscopy in conjunction with hydrogen adsorption to probe surface layer composition, we observe a reversible place exchange between Ge and Si on Ge-covered Si(001) when the surface is dosed with atomic H at elevated temperatures. First-principles calculations confirm a thermodynamic driving force for this place exchange. To expla...
New paths were designed for the investigations of the β-tin→Imma→sh phase transitions in nanocrystalline Ge under conditions of hydrostatic stress. A second-order transition between the β-tin and Imma phases was identified at 66 GPa, and a first-order transition between the Imma and sh phases was determined at 90 GPa. Superconductivity was obtained up to 190 GPa using the acquired structural da...
The principle of Le Chatelier was used in demonstrating that 3-chloro-4,4-dimethyl-2-oxazolidinone (compound 1) itself kills Staphylococcus aureus rather than the very small amount of free chlorine in hydrolysis equilibrium with compound 1. On the other hand, when the N-bromo analog of compound 1 (compound 1B) was used as the disinfectant, the mixture of combined compound 1B and free bromine fo...
EXAMINATION OF NONSTERILE Preparation of Test Strains PRODUCTS: MICROBIAL Use standardized stable suspensions of test strains or prepare as stated below. Seed-lot culture maintenance techENUMERATION TESTS niques (seed-lot systems) are used so that the viable microorganisms used for inoculation are not more than five passages removed from the original master seed-lot. Grow each of the bacterial ...
The angular sensitivity of Brewster-angle reflection polarizers (BARP) is first studied approximately by determining the Taylor series expansion of the parallel reflectance R(p) as a function of angle of incidence ø near the Brewster angle ø(B). Subsequently, exact and explicit equations are derived that determine the lower and upper limits, ø(l) and ø(u), of the range of ø, that includes ø(B),...
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