A series of Pd(en)X2 salts were used as catalysts for the conversion of aldoximes into nitriles and amides. Highlights of this protocol include the use of inexpensive polar solvents, including water, and moderate reaction temperatures. A high degree of selectivity in the reaction outcome was observed when using aliphatic vs. aromatic/conjugated aldoximes.

Introduction. Cysteine is the one of the sulfur containing non-essential amino acids along with methionine, which are found naturally in many proteins such as α and β-ceratins, and in free state. The ability of cysteine residues to form disulfide bridges plays an important role on secondary structure and folding of proteins. Another prominent quality is that sulfur can be found in different oxi...

A direct nitration of aromatic sulfonamides using sodium nitrite as the nitrating agent has been developed. The reaction shows typically mono-substitution selectivity and can be enlarged to the gram scale with good yield.

Bis-phosphine oxides can be selectively reduced to bis-phosphine monoxides under exceptionally mild conditions using triflic anhydride and a thiol.

We prove new existence results of mild solutions to fractional differential equations with nonlocal conditions in Banach spaces. The nonlocal item is only assumed to be continuous. This generalizes some recent results in this area.

An aldol-type reaction of organonitriles with aldehydes was catalyzed by a RhI(OR) species under ambient conditions, and the reaction displayed a broad substrate scope with respect to both organonitrile and aldehyde components.

in this paper, we consider a class of time-dependent neutral stochastic evolution equations with the infinite delay and a fractional brownian motion in a hilbert space. we establish the existence and uniqueness of mild solutions for these equations under non-lipschitz conditions with lipschitz conditions being considered as a special case. an example is provided to illustrate the theory

1,8-dioxo-decahydroacridines have been synthesized by the three-component reaction of aromatic aldehydes, aromatic amines (or ammonium acetate), and dimedone in the presence of sulfonic acid functionalized nanoporous silica (sba-pr-so3h) under solvent-free conditions. excellent yields, short reaction times, mild reaction conditions, and easy work-up procedures are advantages of this green method.

This study was conducted to investigate the use of cubic LaMnO3 nano-perovskite as a green catalyst for the degradation of an aqueous solution of methyl orange under different conditions. Nanoscale cubic lanthanum manganite with the particle size of ~20 nm was successfully synthesized via citrate sol-gel method. The sample was characterized using the FT-IR and UV-Vis spectroscopy, XRD, SEM, and...