MIL-53(Fe) was prepared and modified with benzoic acid to prepare MIL-53(Fe)-BA additive, which used improve the catalytic oxidation rate of sulfite, prevent scaling desulfurization tower, efficiency during wet flue gas (WFGD) process power plants. exhibits abundant Lewis sites because appearance coordination unsaturated Fe atoms. Due excellent sorption capacity, Ca(OH)2 as main SO2 desulfurize...

Heterojunction catalysts have drawn increasing interest for the visible light-driven Fenton reaction and bring tremendous opportunities environmental remediation. Herein, a BiOI/MIL-53(Fe) Z-scheme heterojunction (named BMFe) was synthesized first time via facile strategy. Compared with pristine BiOI MIL-53(Fe) catalysts, two-dimensional/three-dimensional (2D/3D) catalyst manifested remarkable ...

A molecular H2-evolving catalyst, [Fe2(cbdt)(CO)6] ([FeFe], cbdt = 3-carboxybenzene-1,2-dithiolate), has been attached covalently to an amino-functionalized MIL-101(Cr) through an amide bond. Chemical reduction experiments reveal that the MOF channels can be clogged by ion pairs that are formed between the oxidized reductant and the reduced catalyst. This effect is lessened in MIL-101-NH-[FeFe]...

Hydrothermally stable particles of the metal-organic framework MIL-101(Cr) were incorporated into a polysulfone (PSF) matrix to produce mixed-matrix or composite membranes with excellent dispersion of MIL-101 particles and good adhesion within the polymer matrix. Pure gas (O2, N2, CO2 and CH4) permeation tests showed a significant increase of gas permeabilities of the mixed-matrix membranes wit...