Robust Ru nanoparticles created by exsolution enhanced the chemical looping methane reforming performance for stable syngas production and CO2 splitting

The CO2 (dry) reforming of hydrocarbons offers an opportunity to convert greenhouse gases into synthesis gas, which can further transform various valued products. Here we explore the influence Rh particle size and support on propane methane. To that end, nanoparticles with controlled sizes varying from 1.6-8.0 nm were synthesized following a polyol reduction method then dispersed three differen...

This study investigates use of solar thermochemical processing of clean fuels using biomass products (in particular CH4, H2O). To address technological feasibility of a microchannel-based solar receiver/reactor, a combined numerical and experimental study of methane-steam reforming is carried out on a single microchannel with Palladium-deposited channel walls and heat input to facilitate endoth...

It has been demonstrated both thermodynamically and experimentally that fuel-cell grade hydrogen can be produced by a one-step sorption enhanced water gas shift (SEWGS) process at about 500 oC, where the water gas shift (WGS) catalyst and the CO2 sorbent are highly integrated. A synthetic CaO-based mixed oxide sorbent was also assessed, which showed a good CO2 capture capacity and stability in ...

A rise in CO2 and other greenhouse gases’ concentration from gas refinery flares and furnaces in the atmosphere causes environmental problems. In this work, a new process was designed to use waste gas (flue gas and flare gas) of a domestic gas refinery to produce pure hydrogen in a membrane reactor. In particular, the process foresees that the energy and CO2 content of flue gas can provide the ...

Catalytic partial oxidation (CPOX) has recently received particular attention because it is one of the most attractive technologies for the production of syngas and hydrogen in small to medium scales. Current study subjected to partial oxidation reforming which have simultaneously studied the effect of the fuel composition and flow rates of methane-oxygen mixed gas on the SOFCs performances. In...

Methane reforming allows the production of synthesis gas (syngas) which is an important mixture feedstock for chemicals and energy carriers. Steam methane (SRM) partial oxidation (POM) have been deployed at large industrial scale, while dry (DRM) more recently tri-reforming (TRM) are intensively studied. TRM simultaneously combines SRM, POM DRM in a unique process overcoming several weaknesses ...

Carbon deposition following thermal methane decomposition under dry and steam reforming conditions has been studied on yttria-stabilized zirconia (YSZ), Y2O3, and ZrO2 by a range of different chemical, structural, and spectroscopic characterization techniques, including aberration-corrected electron microscopy, Raman spectroscopy, electric impedance spectroscopy, and volumetric adsorption techn...

The chemical looping reforming (CLR) process, which utilizes a transition metal oxide based redox catalyst to partially oxidize methane to syngas, represents a potentially efficient approach for methane valorization. The CLR process inherently avoids costly cryogenic air separation by replacing gaseous oxygen with regenerable ionic oxygen (O(2-)) from the catalyst lattice. Our recent studies sh...