ACRYLATES HAVE been around since the 1930s, when Rohm and Haas began mass production of Plexiglas, a clear and resistant glass substitute made of polymerized methacrylate. It is used extensively for windowpanes, airplane canopies, car lights and windshields, streetlamps, and so on. Numerous other acrylates have been synthesized and have found applications in paints and adhesives, dental composi...

This work describes the development of magnetic levitation (MagLev) to characterize the kinetics of free-radical polymerization of water-insoluble, low-molecular-weight monomers that show a large change in density upon polymerization. Maglev measures density, and certain classes of monomers show a large change in density when monomers covalently join in polymer chains. MagLev characterized both...

OBJECTIVE To evaluate the coronal microleakage of packable composite using conventional incremental and posterior bulk fill flowable composite using Smart Dentine Replacement Single Step technique in the cervical margins of class II cavities in dentine using the dye penetration method. STUDY DESIGN In-vitroInterventional study. PLACE AND DURATION OF STUDY Department of Operative Dentistry, ...

Hybrid-layer degradation occurs because of acidic properties of currently used adhesive systems. Titanium tetrafluoride couples with tooth surface, and titanium compounds are not substituted. Caffeic acid phenethyl esther inhibits endogenous matrix metalloproteinases that cause hybrid-layer degradation. It was hypothesized that titanium tetrafluoride and caffeic acid phenethyl esther applicatio...

With increasing interest in the development of new composite systems for a variety of applications which require easily processible materials and adequate structural properties with high energy densities, we have pursued the chemical functionalization of oxide passivated aluminum nanoparticles (nAl) using three acrylic monomers, 3‐(trimethoxysilyl)propyl methacrylate (MPS), 2‐carboxyethyl acryl...

The eMcacy of pretreatment on the dentin surface with an aqueous solution of glycery1 methacrylate {GM) was examined by measuring the wall-to-wall polymerization centraction of a light activated composite in a cylindrical dentin cavity, and by measuring the tensile bondi strength to a flat dentin surface. All of the tested dentin surfaces were cleaned with neutralized O.5M EDTA and treated with...

Effects of modifying oil palm mesocarp fibers (OPMF) by methacrylate silane on polylactic acid (PLA)/ polycaprolactone (PCL)/clay/OPMF hybrid composites were investigated. The composites were prepared by a melt blending technique and characterized by dynamic mechanical analysis (DMA) and scanning electron microscopy (SEM). The silane-treated OPMF hybrid composites showed better tensile strength...

The efficacy of pretreatment on the dentin surface with an aqueous solution of glyceryl methacrylate (GM) was examined by measuring the wall-to-wall polymerization contraction of a light activated composite in a cylindrical dentin cavity, and by measuring the tensile bond strength to a flat dentin surface. All of the tested dentin surfaces were cleaned with neutralized 0.5 M EDTA and treated wi...

Electromagnetic interference (EMI) shielding effectiveness (SE) of multi-walled carbon nanotubes-polymethyl methacrylate (MWCNT-PMMA) composites prepared by two different techniques was measured. EMI SE up to 40 dB in the frequency range 8.2-12.4 GHz (X-band) was achieved by stacking seven layers of 0.3-mm thick MWCNT-PMMA composite films compared with 30 dB achieved by stacking two layers of 1...

Latex nanoparticles comprising cationically charged coronas and hydrophobic cores with different glass transition temperatures (Tg) have been prepared by surfactant-free, RAFT-mediated emulsion polymerization, where the particles form through a polymerization-induced self-assembly (PISA) type mechanism. Poly(2-dimethylaminoethyl methacrylate-co-methacrylic acid) (P(DMAEMA-co-MAA)) was utilized ...