A simple isotherm model has been developed for the type-5 equilibrium adsorption systems by considering the effects of both primary and secondary adsorptive sites. The model was applied to interpret experimental data describing water vapor adsorption capacities of four activated carbon adsorbents for relative vapor pressures from 0.0 to 0.95 and temperatures between 288 and 308 K. Good agreemen...

The progresses of understanding of the surfactant adsorption at the hydrophilic solid-liquid interface from extensive experimental studies are reviewed here. In this respect the kinetic and equilibrium studies involves anionic, cationic, non-ionic and mixed surfactants at the solid surface from the solution. Kinetics and equilibrium adsorption of surfactants at the solid-liquid interface depend...

Three isotherm models were used to describe adsorption equilibrium of a toxic chemical compound, phenol, onto a non porous adsorbent (Mediterranean Posidonia oceanica fibres) and a porous adsorbent, activated carbon prepared from Caribbean Vetiveria zizanoides roots. The adsorption characteristic parameters obtained were calculated using classical adsorption isotherm, i.e. the Langmuir (LI), Fr...

Low-pressure high-resolution hydrogen adsorption for the metal-organic framework MIL-101 are measured at 19.5 K and pressures below 57 kPa. The BET specific surface area and micropore volume are determined and compared to results from nitrogen adsorption at 77 K. Steps in the hydrogen adsorption isotherm are correlated to the pore structure of MIL-101.

The preparation and testing of thiol-functionalised silica-coated magnetite nanoparticles (TF-SCMNPs) is described. The characteristics of these particles are assessed at different stages in the production process using X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier Transform Infrared Spectroscopy (FTIR), and a magnetometer. The particles were found to be almost spheri...

BACKGROUND In order to remove heavy metals, water treatment by adsorption of zeolite is gaining momentum due to low cost and good performance. In this research, the natural mordenite was used as an adsorbent to remove lead ions in an aqueous solution. METHODS The effects of adsorption temperature, time and initial concentration of lead on the adsorption yield were investigated. Response surfa...

The di€erential capacitance of a polycrystalline Ag electrode was measured in a NaClO4 electrolyte containing Na2S2O3 at concentrations ranging from 0.1 to 20mM and at electrode potentials ranging from )0.9 to )0.3V vs SCE. The di€erential capacitance measurements were analysed to obtain the surface coverage of speci®cally adsorbed thiosulfate (S2O 2ÿ 3 ) as a function of both electrode potenti...

The adsorption of Cr(III) and As(III) by using coal ash from thermal power plants in batch mode ,The effect of adsorbent agitation speed, dose, pH, contact time and agitation speed on the adsorption of Cr(III) and As(III) by coal ash is examined. Adsorption equilibrium was achieved in 50–55 min. The Langmuir, Temkin and Freundlich adsorption isotherms were used to observed sorption phenomena. T...

Reaction of NiCl2·6H2O, D-camphoric acid (D-H2cam), and N,N′-bis(pyraz-2-yl)piperazine (bpzpip) in pure water at 150 ◦C afforded a novel nickel(II) coordination layer, [Ni4(D-cam)2(D-Hcam)4(bpzpip)4(H2O)2] (1), under hydro(solvo)thermal conditions. Single-crystal X-ray structure analysis reveals that 1 adopts a six-connected two-dimensional (2D) chiral layer structure with 36-hxl topology. Dye ...

This paper reports on the direct ability of two positively charged organic polyelectrolytes (natural-based and synthetic) to reduce the atrazine concentration in water. The adsorption study was set up using multiple glass vessels with different polymer dosing levels followed by ultrafiltration with a 1 kDa membrane. The addition of polymers exhibited a capability in reducing the atrazine concen...