Abstract The electrochemistry of catalase (CAT) was investigated at the interface between two immiscible electrolyte solutions (ITIES) as a step towards its detection. Electrochemistry ITIES offers advantages such non-redox detection biomolecules. electrochemical behaviour CAT ITIES, in micro-interface array format, displayed distinct cyclic voltammogram when aqueous phase pH lower than isoelec...

The MIT Faculty has made this article openly available. Please share how this access benefits you. Your story matters. With molecular simulation for water and a tunable hydrophobic substrate, we apply the instantaneous interface construction [A.] to examine the similarity between a water-vapor interface and a water-hydrophobic surface interface. The intrinsic interface refers to molecular struc...

We numerically investigate the nonlinear evolution of the interface of a thin liquid-vapor bilayer system confined by rigid horizontal walls from both below and above. The lateral variation of the vapor pressure arising from phase change is taken into account in the present analysis. When the liquid vapor is heated cooled and gravity acts toward the liquid, the deflection of the interface monot...