A fundamental study on the adsorption of metal elements on Shirasu, a pyroclastic flow deposit distributed in southern Kyushu, Japan, has been conducted. The adsorption experiment was carried out by a batch method, and by using Zn(II) and Cu(II) under several conditions; the effects of the initial concentration of metal ions, grain size, and pH were investigated. At smaller grain sizes, the amo...

Adsorption process is an important technique in separation processes, which is used in heavy metals removal from aqueous solution. Orange peel has been investigated for the adsorption of uranium ions from aqueous solution. The parameters of pH, contact time, initial uranium ion concentration, temperature and adsorbent dose have been investigated in batch experiments. The adsorption kinetics wer...

Catalytic waves obtained from the perchloric acid-soluble fraction of serum in the presence of hexaminecobalt trichloride appear to conform to a Langmuir adsorption isotherm. Wave heights for sera from patients with untreated urological cancers significantly exceed those from normal subjects. In general, treatment with diethylstilbestrol decreased the wave height. Effects of some other chemothe...

The adsorption of polyester onto organically modified silicas (ormosils) and (commercial) fumed silica has been compared utilising ToF-SIMS. The thermodynamics of each system was examined by constructing adsorption isotherm plots which indicated that the adsorption of polyester onto one of the modified silicas used may be a two stage process. Adsorption onto the fumed silica is in accord with t...

The potential of activated carbons--powdered (PAC) and granular (GAC), for the adsorption of acrylonitrile (AN) at different initial AN concentrations (50<or=C(0)<or=500 mg/l) from aqueous solutions was studied over the temperature range of 303-333 K. The effect of adsorbent dosage, initial AN concentration, contact time, and the change in pH with addition of adsorbents on adsorption was studie...

Sorption of P to the bed sand medium is a major removal mechanism for P in subsurface flow constructed reed beds. Selecting a sand medium with a high P-sorption capacity is therefore important to obtain a sustained P-removal. The objective of this study was to evaluate the P-removal capacities of 13 Danish sands and to relate the removal to their physico-chemical characteristics. The P-removal ...

A new chelating resin was prepared by coupling Amberlite XAD-4 with alizarin red-s through an azo spacer, characterized by infra-red spectroscopy and thermal analysis and studied for Rh(III) preconcentration using inductively coupled plasma atomic emission spectroscopy (ICP-AES) for rhodium monitoring in the environment. The optimum pH for sorption of the metal ion was 6.5. The sorption capacit...

Microwave stabilized heavy metal sludge was used as an adsorbent to remove the copper ions from aqueous solution. The adsorption characteristics of copper on the stabilized-sludge were studied by various models, such as Freundlich and Langmuir isotherm equation. Results show that the pH(zpc) of stabilized-sludge was at 9.2-9.5. Moreover, the adsorption of copper ions onto the stabilized-sludge ...

Spectral confocal microscope visualizations of microsphere movement in unsaturated porous media showed that attachment at the Air Water Solid (AWS) interface was an important retention mechanism. These visualizations can aid in resolving the functional form of retention rates of colloids at the AWS interface. In this study, soil adsorption isotherm equations were adapted by replacing the chemic...

The potential of water hyacinth ash for phenol adsorption from aqueous solution was studied. Batch kinetic and isotherm studies were carried out under varying experimental conditions of contact time, phenol concentration, adsorbent dosage and pH. The adsorption of phenol decreased with increasing pH. The Freundlich and Langmuir adsorption models were used for the mathematical description of ads...