The parameter estimation using the traditional kinetic modeling of complex reaction systems will give incorrect results if the reaction mechanism contains a loop. In this work, a thermodynamically consistent kinetic model of the anodic electrochemical hydrogen oxidation reaction mechanism of a solid oxide fuel cell (SOFC) is formulated. An iterative algorithm for estimating the reaction rate co...

in this work, based on experimental observations and exact theoretical predictions, the kinetic scheme of raft polymerization is extended to a wider range of reactions such as irreversible intermediate radical terminations and reversible transfer reactions. the reactions which have been labeled as kinetic scheme are the more probable existing reactions as the theoretical point of view. the deta...

even purified enzyme preparations are often heterogeneous. for example, preparations of aspartate aminotransferase or cytochrome oxidase can consist of several different forms of the enzyme.  for this reason we consider how different the kinetics of the reactions catalysed by a mixture of forms of an enzyme must be to provide some indication of the characteristics of the species present.  based...

An adsorption-kinetic model has been proposed to explain -galactosidase stability in a recirculation hollow-fibre bioreactor at different temperature. The kinetic constants of the model and its dependence on temperature have been evaluated. In addition, a study has been made of the influence of lactose and enzyme concentration on lactose hydrolysis with hollow-fibre modules m s a m a ©

A mathematical model for the interaction kinetic in phage-bacterium culture is proposed. An appropriate analytical relationship between phage and bacterial concentrations has been derived. Characteristic kinetic constants have been obtained by comparing the experimental growth curves with computer-simulation analysis. The model allows also to evaluate the phage-yield as a function of the initia...

Freshwaters are recognized as dynamic systems that may be far-removed from equilibrium. A kinetic approach using the competing ligand exchange method with Chelex 100 as the competing ligand and inductively coupled plasmamass spectrometry to measure the dissociation kinetics was used to investigate the chemical speciation of Mn(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II), and Pb(II) in model sol...

The rate of formation of angiotensin was investigated for the reaction of angiotensinase-free human renin, at various states of purity, with angiotensinogen, in pooled, angiotensinase-free human serum. The velocity constant of this reaction and the Michaelis constant of the rerun-substrate complex were determined. The concentration of angiotensinogen and of endogenous renin in human serum was a...

The rate of formation of angiotensin was investigated for the reaction of angiotensinase-free human renin, at various states of purity, with angiotensinogen, in pooled, angiotensinase-free human serum. The velocity constant of this reaction and the Michaelis constant of the rerun-substrate complex were determined. The concentration of angiotensinogen and of endogenous renin in human serum was a...

The reactions of propenyl magnesium halides with ethylene were studied using ab initio calculations. The structure of the transition state and the ground state were evaluated and obtained the structural properties, theoretical thermodynamic and kinetic data i.e. rate constants of the reactions. The methods used for calculations are RHF, B3LYP and MP2 with 6-31G* b...

This paper presents the influence of Hybrane H 1500 as a hyperbranched polymer on kinetic parameters of dyeing compounded fiber grade PET polyethylene terephthalate at boil temperature. C.I. Disperse Red 324 as a disperse dye was used for dyeing compounded fiber grade PET. The result was compared with corresponding properties of virgin PET. The dyeing rate constants and diffusion coefficients a...