Pd–Ag alloys are largely used as hydrogen separation membranes and, a consequence, the Pd–Ag–H system has been intensively studied. On contrary, fewer information is available for Pd–Ag–D system; thus, aim of this work to improve knowledge isotope effect on commercial Pd77Ag23 alloy, especially temperature above 200 °C. In particular, deuterium absorption measurements carried out in alloy range...