The oxygen isotope composition of nitrogen oxides (NOx) in the atmosphere is a useful tool for understanding the oxidation of NOx into nitric acid / nitrate in the atmosphere. A set of experiments was conducted to examine change in isotopic composition of NOx due to NOx–O2– O3 photochemical cycling. At low NOx / O2 mixing ratios, NOx became progressively and nearly equally enriched in 17O and 1...

Using the Solar Isotope Spectrometer (SIS) on the Advanced Composition Explorer (ACE), we have measured the isotopic composition of as many as eleven elements from He through Ni at energies of tens of MeV /nucleon in eleven solar energetic particle (SEP) events that have occurred since November 1997. We find that isotopic composition varies dramatically from event to event. For example, the 22N...

The stable isotopic composition of drinking water, diet, and atmospheric oxygen influence the isotopic composition of body water ((2)H/(1)H, (18)O/(16)O expressed as δ(2) H and δ(18)O). In turn, body water influences the isotopic composition of organic matter in tissues, such as hair and teeth, which are often used to reconstruct historical dietary and movement patterns of animals and humans. H...

Carbon cycle disturbance associated with mass extinction at the end of the Permian Period continued through the Early Triassic, an interval of approximately 5 million years. Coincidence of carbon cycle stabilization with accelerated Middle Triassic biotic recovery suggests a link between carbon cycling and biodiversity, but the cause of Early Triassic carbon isotope excursions remains poorly un...

We report novel analytical procedures allowing for the concurrent determination of the stable and mass-independent Cr isotopic composition of silicate materials by multiple collector inductively coupled mass spectrometry (MC-ICPMS). In particular, we focus on improved precision of the measurement of the neutron-rich isotope 54Cr. Because nitride and oxide interferences are a major obstacle to p...