The incorporation of an organic group into sol-gel-derived silica causes significant changes in the structure and properties of these materials. Therefore, the thermal treatment of organosilica materials may require a different approach. In the present paper, kinetic parameters (activation energy, pre-exponential constant, and reaction models) have been determined from mass loss data for the de...

The methods of thermogravimetric analysis (TGA) and differential scanning calorimettry (DSC) have been used to study the thermal decomposition of ammonium perchlorate (AP). TGA curves obtained under both isothermal and nonisothermal conditions show a characteristic slowdown at the extents of conversion, R ) 0.30-0.35. DSC demonstrates that in this region the process changes from an exothermic t...

The kinetic properties and thermal characteristics of fresh pork meat proteins (Longissimus dorsi), as well osmotically dehydrated proteins, were investigated using differential scanning calorimetry. Two isoconversional kinetical methods, namely the Friedman integral Ortega employed to analyze data. obtained triplet, activation energy, pre-exponential factor, extent conversion, has been discuss...

An enhanced general analytical equation has been developed in order to evaluate the kinetic parameters of the thermal degradation of nanocomposites, composed of poly(lactic acid) (PLA) and organo-modified montmorillonite (OMMT) nanoparticles. This improvement has consisted of replacing the n-order conversion function by a modified form of the Sestak-Berggren equation that led to a better adjust...

Abstract Colloidal ferric oxide/aluminum nanothermite mixture was incorporated into ammonium percholorate (AP). Nanothermite particles experienced an increase in AP decomposition enthalpy by 120% using DSC. Decomposition kinetic study performed integral isoconversional models including Kissinger and KAS models. offered decrease activation energy 55 44% models, respectively. nanocomposite is run...