a new carboxylic acid extractant, named 2-(dibutylcarbamoyl)benzoic acid, is prepared and its potential for selective solvent extraction and recovery of lead ions from industrial samples was investigated. the slope analysis indicated that the lead ions are extracted by formation of 1:2 metal to ligand complexes. the effect of the parameters influencing the extraction efficiency including kind o...

the sorption behavior of loofa-immobilized phanerochaete chrysosporium mycelia in two forms, live (l) and heat-inactivated (hia), was studied for the removal of hg2+ ions from aqueous solution. using the langmuir isotherm, the two key parameters for the sorption performance, qm and the coefficient b, were obtained; the qm values for hg2+ ions were 72.46 mg/g and 92.59 mg/g and the b coefficient...

metal ions are the main impurities of water and media ingredients used in fermentation processes. in this research, the effect of ca+2, co+2, cu+2, fe+2, mg+2, mn+2 and zn+2 as chloride and sulfate salts was studied on the clavulanic acid production and streptomyces clavuligerus growth. all chloride salts had negative effect on clavulanic acid production and no clavulanic acid was produced in t...

the interaction of hgh with some metal ions ( ) at 27°c in nac1 solution, 50 mm was studied using isothermal titration calorimetry. there is a set of three identical and non-interacting binding sites for binding of all these metal ions, expect . the intrinsic association equilibrium constants () are not very different for  and , and also their molar enthalpies of binding (kj/mol for  and  kj/mo...

europium (eu) doped zno microsphere based nano-sheets were synthesized through hydrothermal method. effects of different concentrations of europium on structural and optical properties of zno nano-sheets were investigated in detail. prepared un-doped and eu-doped zno samples were characterized using x-ray diffraction (xrd), energy dispersive x-ray spectroscopy (edx), scanning electron microscop...

the complexation reactions between tl+ and pb2+ ions and crown ethers 12-crown-4(12c4), 15-crown-5 (15c5), benzo-15-crown-5 (b15c5), 18-crown-6 (18c6), dicyclohexyl-18-crown-6 (dc18c6) and aza-18-crown-6 (a18c6) were studied in 90% acetonitrile and 90% ethanol solutions at 25 °c, using an a.c. polarographic technique. the stoichiometry and stability of the complexes were determined by monitorin...

in this research, nanoporous silica (sba-15) was physically functionalized using2-(2-nitrobenzylideneamino) guanidine compound. this functionalized sba-15 was utilized as a new sorbentfor separation and preconcentration of some lanthanide ions. inductively coupled plasma optical emissionspectrometry (icp-oes) was used as a detection technique. the preconcentration factor of the method is 100and...