On the propagation of resonant radiation through an optically dense system, photon capture is commonly followed by one or more near-field transfers of the resulting optical excitation. The process invokes secondary changes to the local electronic environment, shifting the electromagnetic interactions between participant chromophores and producing modified intermolecular forces. From the theory ...

Thin liquid films arise in many technological applications and biological phenomena. They also present a fascinating object of study, because rich interplay between capillarity, hydrodynamics, interfacial transport phenomena rheology, as well the effects interaction forces when thin down to molecular thicknesses. Recent advances experimental techniques have given further insights variety physic...

A controversial point in fluid dynamics is to distinguish the relative importance of surface roughness and fluid-surface intermolecular interactions in determining the boundary condition. Here hydrodynamic forces were compared for flow of Newtonian fluids past surfaces of variable roughness but similar, poorly wetted, surface chemistry. The critical shear stress and shear rate to observe deviat...

Analytical forces have been derived in the Lagrangian framework for several random phase approximation (RPA) correlated total energy methods based on the range separated hybrid (RSH) approach, which combines a short-range density functional approximation for the short-range exchange-correlation energy with a Hartree-Fock-type long-range exchange and RPA long-range correlation. The RPA correlati...

By considering the fact that the surface tension of a real fluid arises from a combination of both repulsive and attractive forces between molecules, a new expression for the interfacial tension has been derived from scaled particle theory (SPT)  based on the work of cavity formation and the interaction energy between molecules. At the critical temperature, the interfacial tension between c...

Using differential quadrature method (DQM), this study investigated pull-in instability of beam-type nano-switches under the effects of small-scale and intermolecular forces including the van der Waals (vdW) and the Casimir forces. In these nano-switches, electrostatic forces served as the driving force, and von-Karman type nonlinear strain was used to examine nonlinear geometric effects. To de...

Hydrogen bonding underpins the properties of a vast array of systems spanning a wide variety of scientific fields. From the elegance of base pair interactions in DNA to the symmetry of extended supramolecular assemblies, hydrogen bonds play an essential role in directing intermolecular forces. Yet fundamental aspects of the hydrogen bond continue to be vigorously debated. Here we use dynamic fo...

We report on the effect of intermolecular forces fluctuations supported liquid films. Using an optically-induced thermal gradient, we form nanometer-thin films wetting liquids glass substrates, where van der Waals are balanced by thermocapillary forces. show that fluctuation dynamics film interface is strongly modified at lower frequencies. Data spanning three frequency decades in excellent agr...