This paper describes an investigation of the influences of chlorine dioxide treatment on fibre surface lignin. The fibre surface characteristics and the interfacial behaviour of the sisal fibre/phenolic resin composites were also studied by SEM, AFM, and XPS. The results show that the surface of the untreated fibre contains a large amount of lignin with granular structure and non-granular struc...

The studies presented here combine experimental and computational approaches to provide new insights into how water structures and penetrates into the organic phase at two different liquid-liquid systems: the interfaces of carbon tetrachloride-water (CCl4-H2O) and 1,2-dichloroethane-water (DCE-H2O). In particular, molecular dynamics simulations are performed to generate computational spectral i...

Pressure-tolerant polymer-glass microfluidic reactors with excellent bonding strength have been fabricated by the simultaneous solidification-bonding (SSB) method, in which a viscous and reactive matrix polymer was cast on the glass substrate with pre-patterned wax as a sacrificial template. Elaborate interfacial chemistry between the matrix polymer and the functionalized glass surface was desi...

This review focuses on electron transfer at the interfaces between metal oxides and dye molecules within the context of the chemical nature of the anchoring functional groups, the structure of the dye molecules and the morphology of the metal oxides. In dye-sensitized metal oxides, the efficiency of interfacial charge separation and hence photon-to-current conversion may be sensitively manipula...

We report in-situ spectroscopic measurements of the structure and orientation of molecules in the interfacial region between the semi-soluble ionic solid CaF2 (fluorite) and an aqueous phase. This paper integrates a series of new experiments with earlier results to give a comprehensive understanding of this very dynamic interface. We employ the surface specific technique, vibrational sum-freque...

Carbon nanotube (CNT) reinforced polymeric composites provide a promising future in structural engineering. To understand the bridging effect of CNT in the events of the fracture of CNT reinforced composites, the finite element method was applied to simulate a single CNT pullout from a polymeric matrix using cohesive zone modelling. The numerical results indicate that the debonding force during...

We report in situ spectroscopic measurements monitoring the adsorption of a series of carboxylate surfactants onto the surface of the semisoluble, ionic solid fluorite (CaF2). We employ the surface-specific technique, vibrational sum-frequency spectroscopy (VSFS), to examine the effect that surfactant adsorption has on the bonding interactions and orientation of interfacial water molecules thro...

To improve the interfacial bonding of sisal fiber-reinforced polylactide biocomposites, polylactide (PLA) and sisal fibers (SF) were melt-blended to fabricate bio-based composites via in situ reactive interfacial compatibilization with addition of a commercial grade epoxy-functionalized oligomer Joncryl ADR@-4368 (ADR). The FTIR (Fourier Transform infrared spectroscopy) analysis and SEM (scanni...

Purpose – The purpose of this paper is to address the problems of interaction of tensile stress-waves with polyurea/fused-silica and fused-silica/polyurea interfaces, and the potential for the accompanying interfacial decohesion. Design/methodology/approach – The problems are investigated using all-atom non-equilibrium molecular-dynamics methods and tools. Before these methods/tools are employe...