Organic-inorganic hybrid materials overcome drawbacks associated with alginate hydrogels. In this work, covalently coupled silica-alginate hybrids were prepared by Schiff base formation and sol-gel reaction using dialdehyde (ADA), (3-Aminopropyl) triethoxysilane (APTES), APTES/tetraethylorthosilicate (TEOS) precursors. The influence of the polysaccharide/inorganic ratio, nature inorganic precur...

In this study we develop a Secondary Inorganic Aerosol (SIA) module for the chemistry transport model MOCAGE developed at CNRM. Based on the thermodynamic equilibrium module ISORROPIA II, the new version of the model is evaluated both at the global scale and at the regional scale. 5 The results show high concentrations of secondary inorganic aerosols in the most polluted regions being Europe, A...

A versatile, low-energy and solvent-free method to access nanoparticles (NPs) of four different transition metals, based on a bottom-up mechanochemical procedure involving milling of inorganic precursors, is presented. Lignin, a biomass waste, was used effectively as a reducing agent, for the first time in a mechanochemical context, to access MNPs where M = Au, Pd, Ru, Re. A series of metal pre...

In this study we develop a secondary inorganic aerosol (SIA) module for the MOCAGE chemistry transport model developed at CNRM. The aim is to have a module suitable for running at different model resolutions and for operational applications with reasonable computing times. Based on the ISORROPIA II thermodynamic equilibrium module, the new version of the model is presented and evaluated at both...

A series of experiments has been conducted in the Caltech indoor smog chamber facility to investigate the water uptake properties of aerosol formed by oxidation of various organic precursors. Secondary organic aerosol (SOA) from simple and substituted cycloalkenes (C5-C8) is produced in dark ozonolysis experiments in a dry chamber (RH∼5%). Biogenic SOA from monoterpenes, sesquiterpenes, and oxy...

Organic–inorganic building blocks are an important class of hybrid materials due to the synergistic versatility organic compounds with robust properties inorganic materials. Currently, growing interest in silica modify physical and chemical network has led increasing organoalkoxysilanes. A general formula R-[Si-(OR’)3]n, OR’ as a hydrolysable alkoxy group R acting functional (n ≥ 1), precursors...

sulfonic acid-based precursors (sap) play an important role in tailoring mesoporous silica’s and convert them to a solid acid catalyst with a bronsted-type nature. these kinds of solid acids contribute to sustainable and green chemistry by their heterogeneous, recyclable, and high efficiency features. therefore, knowing the properties and reactivity of saps can guide us to manufacture a sulfona...

All-inorganic cesium lead bromide perovskite nanocrystals (PNCs) are highly promising candidates for various optoelectronic and photonic devices. However, poor stability upon exposure to moisture toxicity issues significantly limit their applications. A modern strategy on resolving these is the encapsulation of luminescent within transparent inorganic oxide glasses. While procedure effect devel...

Vapor phase infiltration (VPI) is a post-polymerization modification method for infusing inorganic clusters into polymer to create organic-inorganic hybrid materials with properties that are unique from the parent polymer. The of these can vary amount VPI generated loading. However, relationship between processing conditions and loading still not fully understood. In this paper, effects dose pr...

Zn, K, and Cu effects on the structure and surface area and on the reduction, carburization, and catalytic behavior of Fe–Zn and Fe oxides used as precursors to Fischer–Tropsch synthesis (FTS) catalysts, were examined using X-ray diffraction, kinetic studies of their reactions with H2 or CO, and FTS reaction rate measurements. Fe2O3 precursors initially reduce to Fe3O4 and then to metallic Fe (...