The interaction of hydrazine vapors with single-crystal germanium was studied by using the thermogravimetric method. article considers processes taking place on surface Ge up to formation Ge3N4 nitride, in particular, accumulation N2H4+H2O and their etching water vapor contained hydrazine.

The title compound, [[Ti(C(2)H(10)N)(2)(C(11)H(10)N(3))(2)] or Ti(C(11)H(10)N(3))(2)(NEt(2))(2)], was prepared by direct reaction of 2-(N-phenyl-methyl-imino-meth-yl)-1H-imidazole and [Ti(NEt(2))(4)]. The Ti(IV) atom is in a pseudo-octa-hedral coordination environ-ment with the imidazolido-group N-atoms occupying apical positions and amido- and imino-N-atoms cis-located in the equatorial plane....

Reaction of 1-oxo-1,2,3,4-tetrahydrocarbazoles 1a-e with hydrazine hydrate in absolute ethanol afforded N,N'-bis-carbazolylazine derivatives 2a-e. Treatment of compounds 1a-e with hydroxylamine hydrochloride in ethanol with a catalytic amount of pyridine resulted in the formation of 1-hydroxyimino-1,2,3,4-tetrahydrocarbazoles 3a-e. Reduction of 3 with hydrazine hydrate in the presence of pallad...

The germanium nitride and InP nanowires were grown using the pyrolytic decomposition products of hydrazine (N2H4), which was containing 3 mol.% H2O. In a separate set of experiments the quartz microbalance was used to study the interaction of water containing hydrazine with Ge sample in the temperature range of 450-650°C. It was established that up to 500°C only water molecules interact with Ge...

Proton nuclear magnetic resonance (NMR) spectroscopy is employed to characterize the kinetics of base-pair opening in a series of nine-mer duplexes containing different single base mismatches. The imino protons from the different mismatched as well as fully matched duplexes are assigned from the imino-imino region in the WATERGATE NOESY spectra. The exchange kinetics of the imino protons are me...

The present paper describes the synthesis of two Azo-Schiff base named (2-(((2-aminophenyl)imino)methyl)-6-ethoxy-4-((Z)-phenyldiazenyl) phenol, 2-((Z)-((4-aminobutyl)imino)methyl)-6-ethoxy-4-((Z)-phenyldiazenyl)phenol) by diazotization reaction synthesized (3-Ethoxy-2-hydroxy benzaldehyde) with aniline compound to gave Al- Azo – aldehyde and reacted (O-phenylenediamine or1,4-butanediamine) bas...

The nitro group in aromatic nitro compounds containing reducible substituents such as methyl, carboxylic acids and phenols, and halogens are selectively and rapidly reduced at room temperature to the corresponding amines in good yield by employing hydrazine glyoxylate in the presence of zinc powder or magnesium powder. It has been observed that hydrazine glyoxylate is more effective than hydraz...

A series of iron complexes bearing a bis(imino)pyridine ligand were synthesised and examined as precatalysts for homopolymerisation of propylene. The alkyl substituents attached to the aryl group on the imine nitrogen atoms significantly affected the catalytic activity and molecular weight of the obtained polypropylenes. Copolymerisation of propylene and various allyl comonomers catalysed by ir...

A highly enantioselective trapping of protic phosphoramidate ammonium ylides with α-imino esters is reported. The intriguing Rh2(OAc)4 and chiral Brønsted acid co-catalyzed three-component Mannich-type reaction of a diazo compound, a phosphoramidate, and an α-imino ester provides a rapid and efficient access to 2,3-diaminosuccinic acid derivatives with a high level control of diastereo- and ena...

The H-point standard addition method (HPSAM), based on a spectrophotometric measurement for the simultaneous determination of hydrazine and acetylhydrazine, is described. This method is based on the difference between the rates of their reactions with N,N-dimethylaminobenzaldehyde (DAB) in the presence of sodium dodecyl sulfate (SDS) in acidic media. The results showed that hydrazine and acetyl...