Like beads on a string: A synthetic method for the directional construction of strings of spherical fullerenes along stacks of planar oligothiophenes is described. The key to success was the preparation of fullerenes with two solubilizing tri(ethylene glycol) tails (bold) and an aromatic aldehyde for covalent capture by hydrazides along the oligothiophene stacks (red). BOLAG, Alatengbaolige, et...

The title compound, C(10)H(15)N(2)O(4) (+)·Cl(-), was obtained as an unexpected by-product during the synthesis of 1-[2-(substituted ar-yl)]-3-methyl-pyrazol-5-ones. The hydrazide group is essentially planar, with an r.s.m. deviation of 0.020 (2) Å, and is oriented at a dihedral angle of 30.52 (3)° with respect to the benzene ring. In the crystal structure, the cations and anions are linked thr...

Aryl hydrazides are oxidised to acyl radicals through a mechanism involving diimide intermediates that are prone to nucleophilic acyl substitution. This oxidation occurs regardless of the oxidant involved, however there is no evidence that the acyl radical formed undergoes further oxidation to the corresponding acylium ion, even in the presence of strong oxidants. This study may provide insight...

Iodine-catalyzed regioselective sulfenylation of imidazo[1,2-a]pyridines via C(sp(2))-H bond functionalization has been achieved using sulfonyl hydrazides as a thiol surrogate. A library of 3-sulfanylimidazopyridines with broad functionalities was synthesized under metal and oxidant-free practical reaction conditions. This methodology is also applicable for the regioselective sulfenylation of i...

system (1). The studies of Killam (2) and Killam and Bain (3), whieh used convulsant hydrazides and demonstrated thatr GABA has an inhibitory function in the CNS, suggested a role for GABA in neurotoxicology. There are two types of GABA receptors, GABIVA and GABAB, The GABAA receptor is a membrane bound eomplex consisting of at least three binding sites for GABA, benzodiazepines, the barbiturat...

In this work, we have described an alternative alkenylation approach to illustrate the metal-like behaviour of iodine in cross-coupling reactions. Alkenylation could proceed through iodide catalysed radical initiation, radical addition and iodine promoted alkenyl functionality recovery. Catalytic HI elimination similar to the β-hydride elimination of transition metals was realized for the radic...

Abstract The present work highlights the corrosion inhibition action of two indole-3-hydrazides with varying alkyl chain lengths: 2-(1 H -indol-3-yl)acetohydrazide (IAH) and 4-(1 -indol-3-yl)butanehydrazide (IBH) against mild steel (MS) in 0.5 M hydrochloric acid (HCl) solution using electrochemical gravimetric measurement methods. Both IAH IBH behaved as mixed-type inhibitors, their anticorros...

Abstract Novel hydrazone and 1,2,4-triazole-3-thione derivatives were obtained via the reaction of N 1 , 3 ,2-triaryl-6-hydroxy-6-methyl-4-oxocyclohexane-1,3-dicarboxamides with acid hydrazides thiosemicarbazide, respectively. Structure products was proved using IR H NMR spectroscopy methods. Some synthesized compounds tested for antimicrobial activity