A dithienyl unit in a N,C-chelate monoboryl compound has been found to completely stabilize a N,C-chelate boryl chromophore toward photoisomerization. N,C-chelate diboryl compounds that contain a dithienyl unit display a similar high stability toward photoisomerization. This greatly enhanced photostability is attributed to the π → π* transition and luminescence involving the dithienyl uni...

Bidentate benzotriazole-based N-ligands are suited for the preparation of luminescent heteroleptic copper( i ) complexes with noticeable emissions related to 3 MLCT transitions.

A series of heteroleptic Ir(III) metal complexes 1-3 bearing two N-phenyl-substituted pyrazoles and one 2-pyridyl pyrazole (or triazole) ligands were synthesized and characterized to attain highly efficient, room-temperature blue phosphorescence. The N-phenylpyrazole ligands, dfpzH = 1-(2,4-difluorophenyl)pyrazole, fpzH = 1-(4-fluorophenyl)pyrazole, dfmpzH = 1-(2,4-difluorophenyl)-3,5-dimethylp...

Using ligands based on either an acetylacetonate or a dipyrrin moiety appended with pyridyl groups, a series of novel heteroleptic copper(II) and cobalt(III) complexes combining both chelate units such as (acacpy(2))Cu(dpm-py) and (acacpy(2))Co(dpm-py)(2) (acacpy(2) = 1,3-bis(4-pyridyl)-1,3-propanedionate; dpm-py = 5-(4-pyridyl)dipyrrin) have been prepared and fully characterized. These two com...

A new diphosphine ligand assembled on the cyclotriphosphazene platform forms linear chelate and dimetallic bridged complexes with Au(I) and a cis-chelate complex with Pt(II).

study of the nuclear magnetic resonance spectra of glyoxaldihydrazone in dimethylsulfoxide and deuterochlorofonn leads to the conclusion that this compound exists predominantly in non-chelate structure

Biological and nano fertilizers are alternative supplements to chemical security for the sustainability of agricultural production. This study is present investigate effect biological on quantitative qualitative yield cow pea during two crop years (2018-2019 2019-2020) in research farm South Agricultural Research Education Center Kerman province, Iran. experiment was carried out factorial desig...

A series of donor-acceptor heteroleptic open sandwiches with formula CpM-M'Pyl (M = B, Al, Ga; M' = Li, Na; Cp = cyclopentadienyl; Pyl = pentadienyl) has been designed in silico using density functional theory. The most stable complexes are those containing boron as a donor atom. A molecular orbital analysis shows that the s character of the lone pair located at the group 13 element is mainly r...

in order to study the effect of iron chelate (fe-eddha) on some biochemical characteristic of safflower (carthamus tinctorius l.) under two irrigation regimes, a field experiment was set up a split-plot based on randomized block design with four replication in 2011 in a research field of the faculty of agriculture at shahed university. in this study the main plots consisted of two levels of irr...