نتایج جستجو برای: glass transition temperature
تعداد نتایج: 742402 فیلتر نتایج به سال:
We probe the Ioffe-Regel limits of glasses with repulsions near the zero-temperature jamming transition by calculating the dynamical structure factors. The Ioffe-Regel limit (frequency) is reached when the phonon wavelength is comparable to the mean free path, beyond which phonons are no longer well defined. At zero temperature, the transverse Ioffe-Regel frequency vanishes at the jamming trans...
This communication presents a determination of the glass transition of polybutadiene under very high pressure, and raises the problem of the determination of the relative effects of temperature and density on the glass transition, depending on the pressure and temperature conditions. Local structure and slow dynamics were studied, by neutron scattering and calorimetry. To the best of our knowle...
Monte Carlo simulations performed on multiple polymer chains have produced accurate relaxation modulus Gs(t) curves which match the experimental G(t) curves of polystyrene reasonably well, over a wide temperature range around the glass transition region. The inter-segmental interactions, defined in terms of ε* (well depth) and σ (monomer size), exert a strong influence on the modulus, the lengt...
We present zero-temperature simulations for the single-particle density of states of the Coulomb glass. Our results in three dimensions are consistent with the Efros and Shklovskii prediction for the density of states. Finite-temperature Monte Carlo simulations show no sign of a thermodynamic glass transition down to low temperatures, in disagreement with mean-field theory. Furthermore, the ran...
The heats of eutectic melting and devitrification, and the specific heats of the crystalline, glass, and liquid phases have been measured for a Ni,,Zr,, alloy. The data are used to calculate the Gibbs free-energy difference, AGAc , between the real glass and the crystal on an assumption that the liquid-glass transition is second order. The result shows that AG,, continuously increases as the te...
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