A single walled carbon nanotube (SWCNT)-based three-electrode system was fully integrated on glass substrates using a standard microfabrication process and electrochemically characterized using cyclic voltammetry. O(2) plasma functionalization of the SWCNT film working electrode for achieving high sensitivity was voltammetrically optimized with respect to the plasma power and treatment time. Ch...

A hydrogen ion-selective poly(vinyl chloride) membrane electrode was constructed using 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetracyanomethoxycalix[4]arene as a neutral carrier. The electrode showed an apparent Nernstian response in the 2-11.5 pH range with a slope of 54.0 +/- 0.2 mV/pH at 20 +/- degrees C. This electrode showed a rapid response of the emf to changes in the pH, high ion selec...

current study is aimed to compare fluride release in conventional glass ionomer, light-cured glass ionomer and compomers. standard samples from the aforementioned materials were prepared and measured by selective fluride ion electrode in intervals of 24hours, 1,2,3 and 4 weeks in neutral ph of 7 and acidic ph of 4.5. the obtained data represented that fluride ion release decreased in time but t...

In this work the critical aspects of the process sequence developed for fabrication of hybrid polymer microfluidic systems integrating metal electrode pattern and precisely aligned microfluidic structure are discussed in details. Glass and polycarbonate were considered as primary transparent substrate materials for metal (Au, Pt) electrode deposition and the microchannels were formed in multi-l...

A glass electrode apparatus is described with which pH measurements can be made with as small volumes as 2 drops (about 0.14 cc.) of solution. Using this apparatus the change of pH of the vacuolar sap of Nitella, due to the penetration of brilliant cresyl blue, has been readily followed. The sap and the dye have been found to poison the usual type of hydrogen electrode.

Complex electrical-conductivity experimental data sets for the interfacial amorphous phase in copper-core-copper-oxide-shell nanostructured composites have been analyzed using two Kohlrausch-related frequency response models recently developed for analysis of the dispersive electrical response of conductive materials. Such analysis has been carried out for both the precursor (herein referred to...

This paper investigates the role of electrode– dielectric interactions, and barrier materials on leakage current, breakdown voltage, yield and reliability of thinfilm (Ba,Sr)TiO3 capacitors on silicon and glass substrates. The first part of the paper investigates the electrode–dielectric interactions with sputtered Cu and Ni electrodes to identify the mechanisms that lead to high leakage curren...

The interaction of DNA with quercetin was studied using scanning electrochemical microscopy and electrochemical impedance spectroscopy at glass carbon electrode. Information such as the surface coverage of the film and apparent rate constant of the redox active probe in solution was obtained. It is deduced that quercetin interacting with DNA forms a kind of electrochemical inactive supramolecul...

Gallium ultramicroelectrodes for amperometric measurements in scanning electrochemical microscopy were fabricated by introduction of liquid Ga into drawn glass micropipets. Cyclic voltammetry of Ru(NH(3))(6)(3+) and the use of this species for SECM imaging is described. Double-barrel micropipet tips with a Ga amperometric electrode and an ion-selective (K(+)) potentiometric probe can also be co...

Anodic near-infrared electrochemiluminescence (ECL) from CdTe quantum dots was achieved at low potential on a glass carbon electrode and a strategy for greatly enhanced band-gap ECL was presented.