Multicomponent contaminant transport models in groundwater are typically based on assumptions of local geochemical equilibrium on the grid scale. In heterogenous systems there may be significant coupling between transport processes and geochemical equilibrium at smaller than grid block scale. When these processes are upscaled to grid scale, geochemical evolution may take on a kinetic character....

Background: Proteins of various compositions are required by organisms inhabiting different environments. The energetic demands for protein formation are a function of the compositions of proteins as well as geochemical variables including temperature, pressure, oxygen fugacity and pH. The purpose of this study was to explore the dependence of metastable equilibrium states of protein systems on...

The geochemical discriminate diagrams help to distinguish the volcanics recovered from different tectonic settings but these diagrams tend to group the ocean floor basalts (OFB) under one class i.e., as mid-oceanic ridge basalts (MORB). Hence, a method is specifically needed to identify the OFB as normal (N-MORB), enriched (E-MORB) and ocean island basalts (OIB). We have applied Artificial Neur...

This study provides an overview on the development of the guidelines and legislation related to soil contamination in Finland, with the main focus on geochemical baselines. The use of geochemical baseline surveys in the assessment soil contamination in Finland and in some other countries is briefly discussed and the current practices in Finland are presented. Finally, the geochemical baselines ...

Waterflooding remains the most commonly used method to improve oil recovery. Although injected brine type is mainly dependent on its availability, few of characteristics can be controlled during project design. Published laboratory work indicates that adjustment composition cause an increase in production by wettability alteration. This research objective propose a novel four-step framework for...

Molecular organic geochemical proxies are increasingly being utilized to reconstruct past environmental conditions as new tools continue to be discovered and developed. To date, organic geochemical proxies have been developed mainly for use in marine systems and are widely used in paleoceanography. In contrast, organic proxies have been less commonly used on lacustrine sedimentary records. One ...

A two-dimensional model for colloid transport in geochemically and physically heterogeneous porous media is presented. The model considers patchwise geochemical heterogeneity, which is suitable to describe the chemical variability of many surficial aquifers with ferric oxyhydroxide-coated porous matrix, as well as spatial variability of hydraulic conductivity, which results in heterogeneous flo...

The deep subsurface is an enormous repository of microbial life. However, the metabolic capabilities of these microorganisms and the degree to which they are dependent on surface processes are largely unknown. Due to the logistical difficulty of sampling and inherent heterogeneity, the microbial populations of the terrestrial subsurface are poorly characterized. In an effort to better understan...

The geochemical model PHREEQC is capable of simulating a wide range of equilibrium reactions between water and minerals, ion exchangers, surface complexes, solid solutions, and gases. It also has a general kinetic formulation that allows modeling of nonequilibrium mineral dissolution and precipitation, microbial reactions, decomposition of organic compounds, and other kinetic reactions. To faci...