While galvanic exchange is commonly applied to metallic nanoparticles, recently its applicability was expanded to metal-oxides. Here the galvanic exchange is studied in metal/metal-oxide core/shell nanocrystals. In particular Sn/SnO2 is treated by Ag+, Pt2+, Pt4+, and Pd2+. The conversion dynamics is monitored by in situ synchrotron X-ray diffraction. The Ag+ treatment converts the Sn cores to ...

Increasing of population in the world caused overusing natural resources and land destruction. Salinization and sodification are two effects of land destruction. Leaching of soil soluble salts is the most appropriate method to emend and reclaim saline and sodic soils. In this study, Examination of different leaching methods of saline from sodic soils has been evaluated in Veis Area in Khoozesta...

Coupling seed-mediated co-reduction with galvanic replacement for the first time provides a route to trimetallic (Ag-Au-Pd) nanostructures with hollow interiors. Moreover, manipulating the synthetic conditions can suppress galvanic replacement and facilitate formation of trimetallic core@shell (Ag@Au-Pd) nanostructures. These results illustrate the role of seed composition in the synthesis of a...

Optimization of the acid leaching process for Mongolian apatite-based ore containing rare-earth elements (REEs) was studied. The ore contained approximately 10% of REEs as total rare earth oxides, and the major impurities were Ca (33% as CaO) and Fe (23% as Fe2O3). Fe bearing minerals could be removed by passing the sample through a wet high-intensity magnetic separator before leaching. After m...

Beneficial reuse of coal combustion byproducts, e.g., in highway construction, requires an evaluation of metal leaching potential. Metal leaching from high-carbon fly ash in soil mixes typical of highway embankment construction was evaluated using different soil-fly ash mixtures and three common leaching tests: the water leach test (WLT), the Toxicity Characteristic Leaching Procedure (TCLP), a...

Sulphate leaching losses may reduce the long-term possibility of maintaining the S supply of crops in low input farming systems. Sulphate leaching and S balances were investigated in an organic dairy/crop rotation (barley [Hordeum vulgare] → grass-clover [Lolium perenne/Trifolium repens] → grass-clover → barley/pea [Pisum arvénse] → winter wheat [Tritucum aestivum] → fodder beet [Beta vulgaris]...

The effluent treatment plant sludge is one of the major sources of contamination with toxic metals. Since the sludge contains heavy metals, it must be pretreated to reduce the contamination. The heavy metals from the sludge can be reduced/ separated by washing it with a suitable leaching solution. In the present study, the efficiencies of three leaching solutions to remove the contaminants from...

Biocompatible materials used for the fabrication of dental crowns were studied. Patients were treated with Gold, Porcelain and Zirconia crowns. Dental crowns were selected according to patient’s clinical status and needs. We found that Gold crowns had low patient acceptance because of poor aesthetics and high cost. Gold crowns could not be used opposite to amalgam restorations for the fear of g...