Surface enhanced Raman scattering (SERS) and molecular fluorescence are used to probe the structure of a methylene blue monolayer adsorbed onto a sulfur-modified polycrystalline gold electrode. Changes in the wavelength of fluorescence for methylene blue on the gold electrode as compared to dilute solution indicate that the dye molecules' state of aggregation and electronic structure have been ...

A new general synthesis of all four isomers of monobromoindigo is outlined, the synthesis of 4-, 6and 7-bromoindigo being described for the Ðrst time. All four monobromoindigos as well as indigo and the historically important 6,6@-dibromoindigo (Tyrian purple) have been characterized by 1H NMR spectroscopy of their N,N@bis(triÑuoroacetyl) derivatives, by FT-IR and FT Raman spectroscopy, and by ...

ftr-raman spectra of human dental enamel, both laser-irradiated and untreated, are reported. spectra are compared with hydroxyapatite. it is evident that unlike the co2 laser, the nd/yag laser does not induce any chemical change in dental enamel.

Differential profile of membrane lipids and pigments of a Synechococcus sp. cyanobacterial strain cells exposed to blue, green, red and white light are determined by means of liquid chromatography and mass spectrometry or diode array detection. Raman and ATR-IR spectra of intact cells under the diverse light wavebands are also reported. Blue light cells exhibited an increased content of photosy...

New Hofmann type benzene clathrates in the form of M(CyHEA)2Ni(CN)4·2benzene (where CyHEA=2-(1-cyclohexenyl)ethylamine and M=Ni or Cd) have been prepared in powder form and FT-IR and Raman spectra have been reported. The results suggest that title compounds are similar in structure to Hofmann type clathrates and their structures consist of polymeric layers of |M-Ni(CN)4|∞ with the CyHEA molecul...

Fourier transform (FT-) Raman spectroscopy excited with a 1064 nm laser can be used to determine the content of plasticizers in commercial flexible poly vinyl chloride (PVC) products. Our previous study [T. Nørbygaard, R.W. Berg, Analysis of phthalate ester content in PVC plastics by means of FT-Raman Spectroscopy, Appl. Spectrosc. 58 (4) (2004) 410–413]—on detection of the presence of phthalat...

A systematic vibrational spectroscopic assignment and analysis of pregabalin has been carried out by using FTIR, FT-Raman spectral data. The vibrational analysis were aided by electronic structure calculations-hybrid density functional methods (B3LYP) performed with 631G(d,p) basis set. Molecular equilibrium geometries, electronic energies, natural bond order analysis, IR intensities, and harmo...

Kinetics of ring-opening metathesis polymerization (ROMP) of exo,exo-5,6-di(methoxycarbonyl)-7oxabicyclo[2.2.1]hept-2-ene, promoted by the Grubbs’ 1st generation precatalyst, has been effectively monitored by FT-Raman and NMR spectroscopy. Both techniques evidenced similar monomer conversions to be attained under the same reaction conditions. The present FT-Raman study provided information on t...

Introduction Raman spectroscopy is a vibrational spectroscopic technique, based on inelastic scattering of monochromatic light. This technique can provide valuable information about biomolecular changes, associated with neoplastic transformation. The purpose of this study was to find Raman spectral markers for distinguishing normal samples from cancerous ones in different tissues. Materials and...