The electrochemical generation of vinyl carbocations from alkenyl boronic esters and boronates is reported. Using easy-to-handle nucleophilic fluoride reagents, these intermediates are trapped to form fully substituted fluorides. Mechanistic studies support the formation dicoordinated through sequential single-electron oxidation events. Notably, this fluorination features fast reaction times Le...

We systematically explore the shape-dependent catalytic activities of Au nanocrystals toward glucose oxidation in alkaline electrolytes, which is strongly dependent on the shape of the Au nanocrystals. The {100}-bounded cubic Au nanocrystals are significantly more active than the {110}-bounded rhombic dodecahedral and {111}-bounded octahedral Au nanocrystals.

calcium fluoride deposit during fluoride application. uptake and retention of fluoride by saliva depends generally on the concentration of calcium. in this study, the effect of calcium pre-rinse on salivary fluoride concentration after a 900 ppm fluoride mouthwash was investigated.this cross-over double-blind randomized clinical trial was conducted in a girls' dormitory in zahedan university of...

statement of the problem : enamel white spot lesions are one of the problems associated with fixed orthodontic treatment that compromise esthetics. porpuse the aim of this study was to evaluate the effect of fluoride varnish on the improvement of white spot lesions after fixed orthodontic treatment. materials and methods in this randomized clinical trial, 20 patients with at least two white spo...

Systemic toxicity and poor solubility of existing chemotherapeutic drugs piqued an interest in the use of nanocrystals for chemotherapy. To increase cytotoxicity, surface coating of nanocrystals is of interest to enhance tumor targeting and reduce treatment toxicity. As such, we tested in this project various coated paclitaxel nanocrystals on cancer cells for determining the efficacy of surface...

background. regarding the lack of comprehensive systematic review on the efficacy of water fluoridation and prevalence of dental fluorosis, the aim of the current research was to systematically study the prevalence of dental fluorosis at different levels of water fluoride in the world and lay emphasis on the amount of fluoride in drinking water. methods. studies were searched in pubmed, scopus,...

abnormal fluoride levels in drinking water have been associated with adverse health effects. to determine the fluoride content of well waters in enugu, southeastern nigeria, water samples from 50 artisan wells chosen by multistage sampling procedure from the 5 zones of enugu municipality were analyzed in duplicates for their fluoride content. the zonal mean values were 0.60, 0.70, 0.62, 0.62, a...

a facile co-precipitation method for the synthesis of well-dispersed ndfeo3 nanocrystals is developed in the presence of octanoic acid as surfactant. co-precipitation can produce fine, high-purity, stoichiometric particles of single and multicomponent metal oxides. the product is characterized by fourier transform infrared spectroscopy (ft-ir), x-ray diffraction (xrd), scanning electron microsc...

Introduction of systemic and topical fluorides into the prevention and control of dental caries represents the most significant issue in dentistry in the second half of the 20th century. Fluorides have brought a considerable decline in dental caries prevalence especially in countries with advanced economies. However expanding assortment of fluoride-containing preventives and oral cosmetics has ...

clarithromycin (cla), a broad-spectrum macrolide, is a poorly soluble drug with dissolution rate limited absorption. the aim of this investigation was to prepare cla nanoparticles from a ternary ground mixture in the presence of sodium lauryl sulfate (sls) and polyvinyl pyrrolidone (pvp) as co-grinding water-soluble compounds, in order to improve the drug dissolution rate. different weight rati...