We calculate for the first time the full phase diagram of an asymmetric nonadditivehard-sphere mixture. The nonadditivity strongly affects the crystallization and the fluid-fluid phase separation. The global topology of the phase diagram is controlled by an effective size ratio y(eff), while the fluid-solid coexistence scales with the depth of the effective potential well.

In this present study, volume of fluid method in OpenFOAM open source CFD package will be extended to consider phase change phenomena with modified model due to condensation and boiling processes. This model is suitable for the case in which both unsaturated phase and saturated phase are present and for beginning boiling and condensation process needn't initial interface. Both phases (liquid-va...

We investigate the interfacial phase behavior of a binary fluid mixture composed of repulsive point Yukawa particles. Using a simple approximation for the Helmholtz free energy functional, which yields the random phase approximation for the pair direct correlation functions, we calculate the equilibrium fluid density profiles of the two species of particles adsorbed at a planar wall. We show th...

Phase diagrams of some globular proteins have a fluid-fluid transition as well as a fluid-crystal transition. Homogeneous nucleation of the crystal from the fluid phase near the critical point of the fluid-fluid transition is examined. As the fluid-fluid critical point is approached, the number of molecules in the critical nucleus, the nucleus at the top of the free energy barrier to nucleation...

introduction a wide variety of world-class porphyry cu deposits occur in the urumieh-dohktar magmatic arc (udma) of iran.the arc is composed of calc-alkaline granitoid rocks, and the ore-hosting porphyry intrusions are dominantly granodiorite to quartz-monzonite (zarasvandi et al., 2015). it is believed that faults played an important role in the emplacement of intrusions and subsequentporphyry...

Information about the rheological characteristics of the aqueous cytoplasm can be provided by analysis of the rotational motion of small polar molecules introduced into the cell. To determine fluid-phase cytoplasmic viscosity in intact cells, a polarization microscope was constructed for measurement of picosecond anisotropy decay of fluorescent probes in the cell cytoplasm. We found that the ro...

An energy-based, phase field model is developed for the coupling of two incompressible, immiscible complex fluid phases, in particular a nematic liquid crystal phase in a viscous fluid phase. The model consists of a system of coupled nonlinear partial differential equations for conservation of mass and momentum, phase transport, and interfacial boundary conditions. An efficient and easy-to-impl...

The equilibrium as well as nonequilibrium phase behaviors of colloidal dispersions have been investigated using statistical-mechanical theories of fluids and solids in complement with the renormalization-group (RG) theory. It is shown that the osmotic second virial coefficient at the critical point of the fluid-fluid transition varies with the range of attractions and is sensitive to specific f...

Fluid–fluid and fluid–solid phase equilibrium were experimentally determined under pressure on the system methane + heptadecane using a full isibility cell. Measurements were performed using the synthetic method on mixtures ranging from pure heptadecane to 99% of methane. The iquid–solid phase transitions were investigated up to 90 MPa and fluid phase boundary was studied in the temperature dom...