The intimate relationship between Fe and Cu in human nutrition has been recognised for many years. The best-characterised link is provided by caeruloplasmin, a multiCu-binding protein that acts as a serum ferrioxidase and is essential for the mobilisation of Fe from storage tissues. Decreased Cu status has been shown to reduce holo-caeruloplasmin production and impair ferrioxidase activity, lea...

Iron is a transition metal whose physicochemical properties make it the focus of vital biologic processes in virtually all living organisms. Among numerous roles, iron is essential for oxygen transport, cellular respiration, and DNA synthesis. Paradoxically, the same characteristics that biochemistry exploits make iron a potentially lethal substance. In the presence of oxygen, ferrous iron (Fe(...

The effect of adding oxide promoters, at monolayer coverages, to Pd/ceria catalysts was studied for the watergas-shift reaction in 25 torr each of H2O and CO under differential conditions. Oxides of Fe, Tb, Gd, Y, Sn, Sm, Pr, Eu, Bi, Cr, V, Pb, and Mo were added to ceria by wet impregnation of aqueous salts and calcined to 873 K prior to addition of 1 wt% Pd. While most of the oxides had a negl...

It is the purpose of this work to investigate whether it is feasible to develop Finite Element (FE) models that take into account the geometric differences between the lumbar vertebrae of patients. It is also the purpose of this work to determine whether or not such patient specific differences affect the results of the FE analysis in such a significant way that they should be considered in fut...

Though rice is the predominant source of energy and micronutrients for more than half of the world population, it does not provide enough zinc (Zn) to match human nutritional requirements. Moreover, climate change, particularly rising atmospheric carbon dioxide concentration, reduces the grain Zn concentration. Therefore, rice biofortification has been recognized as a key target to increase the...

The adsorption of a metallo-supramolecular coordination polymer (Fe-MEPE) in the cylindrical pores of SBA-15 silica with pure and carboxylic acid (CA) carrying pore walls has been studied. Fe-MEPE is an intrinsically stiff polycation formed by complexation of Fe(II)-acetate with an uncharged ditopic bis-terpyridine ligand. The adsorption affinity and kinetics of the Fe-MEPE chains is strongly e...

A quasi-continuum (QC) method based on the embedded atom method (EAM) potential was employed to investigate the fatigue crack growth and expansion characteristics of single-crystal Fe and Ni under cyclic loading modes I and II. In particular, the crack growth and expansion characteristics of Fe and Ni under cyclic loading were evaluated in terms of atomic stress fields and force–distance curves...