This study addresses the crystallization and multiple melting behavior of a new high temperature semicrystalline polyimide, which is based on an ether diamine (TPER or 1,3 (4) APB) and BTDA dianhydride, both of which are commercially available. It also uses phthalic anhydride to endcap the chains thus improving thermal stability. The polyimide displays a Tg at ca. 230°C and two prominent meltin...

The melting behavior and crystallization kinetics of PBN–PDEN and PBN–PTDEN copolymers were investigated using differential scanning calorimetry. Multiple endotherms were observed in all of the copolymers under investigation, originating from melting and recrystallization processes. By applying the Hoffman–Weeks method, the Tm1 of the a and b¢-PBN phases were derived. The Tm1 value of the b¢-fo...

the nain and ashin ophiolites are located in northeastern isfahan province, in western central-east iranian microplate. pillow lavas are one of the most significant cretaceous rock units. the lower partial melting degree in mantle peridotites of ashin ophiolite, and the derived melt by melting their clinopyroxene caused a more basic (basalt) and enriched nature for the ashin pillow lavas, where...

The crystallization and melting behaviors of linear polylactic acid (PLA) treated by compressed CO(2) was investigated. The isothermal crystallization test indicated that while PLA exhibited very low crystallization kinetics under atmospheric pressure, CO(2) exposure significantly increased PLA's crystallization rate; a high crystallinity of 16.5% was achieved after CO(2) treatment for only 1 m...

The phase behavior of membrane lipids plays an important role in the formation of functional domains in biological membranes and crucially affects molecular transport through lipid layers, for instance, in the skin. We investigate the thermotropic chain melting transition from the ordered Lβ phase to the disordered Lα phase in membranes composed of dipalmitoylphosphatidylcholine (DPPC) by atomi...

High-pressure melting anchors the phase diagram of a material, revealing the effect of pressure on the breakdown of the ordering of atoms in the solid. An important case is molybdenum, which has long been speculated to undergo an exceptionally steep increase in melting temperature when compressed. On the other hand, previous experiments showed nearly constant melting temperature as a function o...

Depression of the melting point of liver tissue rapidly frozen by liquid nitrogen during life provides a means by which the molecular concentration within liver cells may be compared with that of solutions of sodium chloride or of blood or of blood serum. The rising temperature of frozen blood of guinea pig under the conditions of these experiments is retarded when melting occurs, pursues when ...

Temperature, thermal history, and dynamics of Earth rely critically on the knowledge of the melting temperature of iron at the pressure conditions of the inner core boundary (ICB) where the geotherm crosses the melting curve. The literature on this subject is overwhelming, and no consensus has been reached, with a very large disagreement of the order of 2,000 K for the ICB temperature. Here we ...

Three-strand oligonucleotide complexes are employed to assess the effect of base stacking and base pair mismatch on the relative thermodynamic stabilities of oligonucleotide duplexes. The melting behavior of three-strand oligonucleotide complexes incorporating nicks and gaps as well as internal single base mismatches is monitored using temperature-dependent optical absorption spectroscopy. A se...

As theoretical approaches and technical methods improve over time, the field of computer simulations for water has greatly progressed. Water potential models become muchmore complex when additional interactions and advanced theories are considered. Macroscopic properties of water predicted by computer simulations using water potential models are expected to be consistent with experimental outco...