The electronic properties of semiconducting inorganic lead sulfide (PbS) nanocrystals (NCs) and organic linker molecules are dependent on the size NCs as well used ligands. Here, we demonstrate that a weakly binding ligand can be successfully attached to PbS form coupled organic–inorganic nanostructure (COIN) by mixing with strong partner. We use zinc β-tetraaminophthalocyanine (Zn4APc) in comb...

By means of first principles calculations we show that both rutile and anatase phases of bulk TiO2 doped by S, Se or Pb can display substantial decreasing in the band gap (up to 50%), while doping by Zr does not sizably affect the band-gap value. Moreover, the absorption edge is shifted (up to 1 eV) to the lower energy range in the case of TiO2 doped by S or Pb that opens a way to enhancin...

A controllable flower-like Au nanostructure array for surface-enhanced Raman scattering (SERS) was fabricated using the combined technique of the top-down approach of conventional photolithography and the bottom-up approach of electrodeposition. Au nanostructures with a mean roughness ranging from 5.1 to 49.6 nm were obtained by adjusting electrodeposition time from 2 to 60 min. The rougher Au ...

In this study, by using the first-principles calculations based on density functional theory (DFT), electronic aspects of GeP2S monolayer under effect buckling variation parameter (μ = 0, 2, 4, 6) are theoretically investigated PBE-GGA approximation method, and obtained results have been compared with previous similar structures. The imaginary part dielectric function absorption spectra is pres...

We present an extension of the rigorous coupled-wave analysis technique to analyze second-harmonic generation (SHG) in periodic optical nanostructures in the undepleted-pump approximation. We apply this method to analyze SHG in two example nanostructures for which we predict enhanced nonlinearity due to transverse near-field localization of the fundamental optical field in the nonlinear materia...

Multifunctional porous Si nanostructure is designed to optically monitor enzymatic activity of horseradish peroxidase. First, an oxidized PSi optical nanostructure, a Fabry-Pérot thin film, is synthesized and is used as the optical transducer element. Immobilization of the enzyme onto the nanostructure is performed through DNA-directed immobilization. Preliminary studies demonstrate high enzyma...

Superhydrophobic poly(methylmethacrylate) (PMMA) surface with nanostructure was prepared effectively via phase separation and selective solvent method. It is proposed that the cooperation of the nanostructure of PMMA surface and the surface group reorientation leads to the superhydrophobicity of PMMA surface. The superhydrophobic PMMA surface with nanostructure was characterized by scanning ele...