In the present study, two magnolol based main chain benzoxazine polymers (MCBPs) are designed, synthesized and formulated into thiol-ene resins to develop high-performance polymer dielectrics. Initially, thermoset films, Mag-M-4SH-80 Mag-E-4SH-80, obtained respectively using click chemistry. Being post cured via progressive temperature stage, Mag-M/E-4SH-80 performs complete ring opening polyme...