We have measured the short-time and long-time elastic responses to compression of various types of surfactant layers adsorbed at oil-water interfaces. We prepared reasonably monodisperse oil-in-water emulsions with the same surfactants and monitored the time evolution of the emulsion droplets' diameter. We used a broad variety of surfactants (cationic, nonionic, and small polymers) and alkanes ...

Water droplets can jump during vapor condensation on solid benzene near its melting point. This phenomenon, which can be viewed as a kind of micro scale steam engine, is studied experimentally and numerically. The latent heat of condensation transferred at the drop three phase contact line melts the substrate during a time proportional to R (the drop radius). The wetting conditions change and a...

The dynamics of bubble coalescence is studied using a robust numerical model for a multiphase flow system with interfaces. The effects of liquid viscosity and surface tension on bubble coalescence, for which Reynolds number ranges from 10 to 100 and Bond number ranges from 5 to 50, are investigated. It is shown that the numerical model used in this study can accurately capture the complex topol...

Fiber-based coalescers are widely used to accumulate droplets from aerosols and emulsions, where the accumulated droplets are typically removed by gravity or shear. This Letter reports self-propelled removal of drops from a hydrophobic fiber, where the surface energy released upon drop coalescence overcomes the drop-fiber adhesion, producing spontaneous departure that would not occur on a flat ...

This manuscript analyzes the dynamics of coalescence of an incoming aqueous plug with a wetting layer above a hydrophilic surface in the chemistrode. The chemistrode is a recently described (Chen, D.; Du, W.; Liu, Y.; Liu, W.; Kuznetsov, A.; Mendez, F. E.; Philipson, L. H.; Ismagilov, R. F. Proc. Natl. Acad. Sci. U.S.A. 2008, 105, 16843-16848) microfluidic analogue of an electrode, but operatin...

The aim of this paper is to review the key findings about how particle-stabilised (or Pickering) emulsions respond to stress and break down. Over the last ten years, new insights have been gained into how particles attached to droplet (and bubble) surfaces alter the destabilisation mechanisms in emulsions. The conditions under which chemical demulsifiers displace, or detach, particles from the ...

Using an electrical method and high-speed imaging, we probe drop coalescence down to 10 ns after the drops touch. By varying the liquid viscosity over two decades, we conclude that, at a sufficiently low approach velocity where deformation is not present, the drops coalesce with an unexpectedly late crossover time between a regime dominated by viscous and one dominated by inertial effects. We a...

A common feature of many free surface flows—drop/bubble breakup or coalescence and film/sheet rupture—is the occurrence hydrodynamic singularities. Accurately computing such flows with continuum mechanical, multidimensional flow algorithms is a challenging task given these problems’ multiscale nature, which necessitates capturing dynamics occurring over disparate length scales across 5–6 orders...

During dropwise condensation from vapor onto a cooled surface, distributions of drops evolve by nucleation, growth, and coalescence. Drop surface coverage dictates the heat transfer characteristics and depends on both drop size and number of drops present on the surface at any given time. Thus, manipulating drop distributions is crucial to maximizing heat transfer. On earth, manipulation is ach...

The results of a lattice Boltzmann simulation for collisions between two liquid drops in an immiscible liquid in a linear Stokes flow will be presented. The results will be compared with existing experimental results and asymptotic solutions. The mixing of a contaminant that is initially contained in one of the drops will also be discussed and compared with particle tracking simulations. r 2005...