Electrochemical arrays promise utility for accelerated hypothesis testing and breakthrough discoveries. Herein, we report a new high-throughput electrochemistry platform, colloquially called “Legion,” applications in electroanalysis electrosynthesis. Legion consists of 96 electrochemical cells dimensioned to match common 96-well plates that are independently controlled with field-programmable g...

In this work, the combination of the advantages of two-phase catalysis, electrocatalysis and colloid catalysis is presented. It is shown that palladium or gold colloids prepared by citrate reduction can be charged negatively in a heterogeneous two-phase reaction and subsequently used as aqueous catalysts for dehalogenation reactions. This can be regarded as a new type of electrocatalysis. 2002 ...

A Cu-catalyzed tandem dehydrogenation/dehalogenation sequential reaction along with N-arylation has been developed for the synthesis of pyridazinone derivatives in an aerobic and aqueous environment. To achieve the transformation of three chemical bonds in a one-pot reaction, a multifunctional copper catalyst was used which afforded excellent activity, high selectivity, and recyclability. The c...