Deposition processes control the properties of thin films; they can also introduce high residual stresses, which can be relieved by delamination and fracture. Tungsten films with high 1–2 GPa compressive residual stresses were sputter deposited on top of thin (below 100 nm) copper and diamond-like carbon (DLC) films. Highly stressed films store large amounts of strain energy. When the strain en...

Nanocrystalline semiconducting thin films of copper sulphide (Cu2S) were deposited by novel chemical route using aqueous solution of 0.1 M copper chloride, 0.05 M thiourea, complexing agent 10% aqueous ammonia (NH3) and hydrazine hydrate. The characterization and gas sensitivity of as deposited Cu2S thin film sensor have been investigated. The as deposited Cu2S thin films were observed to be ve...

Cu2S thin films have been prepared by vacuum evaporation method from CuS powder. Cu2S was deposited onto precleaned flat glass substrates coated under a pressure of 10 torr at an evaporation rate of 3Å /sec. The resistivity of the vacuum evaporated Cu2S thin films was measured in the temperature range 303K-453K and was found between 10 to 10 ohm cm. This low resistivity is due to degenerate nat...

We present a new type of temperature driven spin reorientation transition (SRT) in thin films. It can occur when the lattice and the shape anisotropy favor different easy directions of the magnetization. Due to different temperature dependencies of the two contributions the effective anisotropy may change its sign and thus the direction of the magnetization as a function of temperature may chan...

The creation of a suitable inorganic colloidal nanocrystal ink for use in a scalable coating process is a key step in the development of low-cost thin film solar cells. We have developed an innovative method of using copper indium gallium disulfide (CIGS) nanocrystals as the building block for the fabrication of bulk CIGSSe thin films. The CIGS nanocrystal ink solution is applied directly on va...

A scalable technique of chemical vapor deposition (CVD) growth of ultra-thin graphitic film is proposed. Ultra-thin graphitic films grown by a one-step CVD process on catalytic copper substrate have higher crystallinity than pyrolytic carbon grown on a non-catalytic surface and appear to be more robust than a graphene monolayer. The obtained graphitic material, not thicker than 8 nm, survives d...

The paper focuses on corrosion phenomena involving copper, corrosive sulphur and solid insulation of oil-immersed transformers. A study of the available mitigation technique such as passivation to reduce the effects of corrosion phenomena is carried out with the commercially available passivator, Irgamet 39 (Toluiltriazole dialkylamine) (ciba), with concentration of 100 ppm. The paper insulated...

The phase and texture of a newly developed solution-processed copper phthalocyanine (CuPc) thin film have been investigated by two-dimensional grazing incidence X-ray diffraction. The results show that it has β phase crystalline structure, with crystallinity greater than 80%. The average size of the crystallites is found to be about 24 nm. There are two different arrangements of crystallites, w...

Radiation enhanced diffusion at the surface of metals has been observed and studied for low-energy nitrogen ions at the surface of copper. The displacement of the target atoms during irradiation creates vacancies and other defects near the surface, thus enhancing the diffusion of implanted materials toward the surface and also into the solid. The mechanism has been studied here by a specia...

This article reports an experimental and theoretical investigation of mercury dissolution from dental amalgams immersed in neutral (noncorrosive) and acidic (corrosive) flows. Atomic absorption spectrophotometric measurements of Hg loss indicate that in neutral flow, surface oxide films formed in air prior to immersion persist and effectively suppress significant mercury release. In acidic (pH ...