Experimental Section S3 Synthesis and Characterization of Scandium Boryl Carbene Complex (2) S4 Synthesis and Characterization of Phenylamido Enolate Complex (3) S4 13C-Labeled Experiments for Complex 3 S5 Synthesis and Characterization of Scandium Alkoxide Complex (4) S5 Synthesis and Characterization of Scandium Pyridyl Complex (5) S6 Figure S1. ORTEP drawings of 5 S6 Synthesis and Characteri...

Synlett 2002, No. 12, Print: 02 12 2002. Art Id.1437-2096,E;2002,0,12,1954,1965,ftx,en;A30202ST.pdf. © Georg Thieme Verlag Stuttgart · New York ISSN 0936-5214 Abstract: Two different synthetic reactions catalyzed by an iridium complex are discussed. The first is allylic alkylation and allylic amination. This reaction proceeds via a -allyl iridium intermediate. The selectivity strongly depends o...

This paper discusses the performance evaluation and availability analysis of ammonia synthesis unit of a fertilizer plant. The fertilizer plant is a complex and repairable engineering system comprises of various units viz. shell gasification and carbon recovery, desulphurization, co-shift conversion, decarbonation, nitrogen wash and ammonia synthesis etc. One of the most important functionaries...

Here, we report the synthesis of a Schiff-base mixed-ligand complex of cadmium(ІІ) in bulk and nano-scales via the precipitation and sonochemical methods, respectively. The complex formula is [Cd(3-bpdh)(3-bpdb)Cl2]n (1), where the ligands are 3-bpdh = 2,5-bis(3-pyridyl)-3,4-diaza-2,4-hexadiene and 3-bpdb = 1,4-bis(3-pyridyl)-2,3-diaza-1,3-butadiene. The structure of mixed-ligand complex (1) wa...