A series of Ce1 ́xCoxO2 ́y precursors were prepared by homogeneous precipitation using urea as a precipitant. The Co/CeO2 catalysts obtained from the Ce1 ́xCoxO2 ́y precursors were used for the steam reforming of ethanol to produce hydrogen. Co ions could enter the CeO2 lattices to form Ce1 ́xCoxO2 ́y mixed oxides at x ď 0.2 using the homogeneous precipitation (hp) method. CeO2 was an excellent suppo...

This article reviews research related to the activation of methane by Ni and Ru using model catalysts, highlighting the surface science work carried out using molecular beams methods and elevated pressure reaction studies. Emphasis is placed on connecting the model studies of surface science with the corresponding results obtained on the analogous ‘real world’ catalysts. These combined studies ...

This chapter reviews recent studies of catalytic reforming of logistic fuels at hightemperature. Aside from steam and autothermal reforming, special consideration is given to partial oxidation conditions. Natural gas, gasoline, diesel, and ethanol containing fuels are discussed. Methane and iso-octane as fuel surrogates are exemplarily used to explain the behavior of the reformers in particular...

b Catalytic steam reforming of methane, methanol, and ethanol over Ni/YSZ: The possible use of these fuels in internal reforming SOFC N. Laosiripojana a,∗, S. Assabumrungrat b a The Joint Graduate School of Energy and Environment, King Mongkut’s University of Technology Thonburi, Bangkok 10140, Thailand b Center of Excellence on Catalysis and Catalytic Reaction Engineering, Department of Chemic...

11 Nanoscale Co and Ni catalysts in silica were synthesized using sol–gel method for hydrogen production from steam reforming of methanol ( 2 −1 N C a a f 1 1 12

Structure-activity relationships of a nanostructured Cu/ZrO2 catalyst for the steam reforming of methanol (MSR) were investigated under reaction conditions by in situ X-ray absorption spectroscopy (XAS) and X-ray diffraction (XRD) combined with on-line mass spectrometry (MS). Temperature programmed activation by reduction in hydrogen or by reduction in a mixture of methanol and water (feed) was...

The effect of ruthenium on the physico-chemical properties of CeZr and CeZrCo mixed oxides for H2 production by glycerol steam reforming reaction has been studied. The combination of in situ Raman spectroscopy under both reductive and oxidative conditions, H2/O2 pulses and XRD, Raman, BET analysis, H2-TPR and TPD-TPO analyses contributed to the determination of the structural and textural prope...

The activation and catalytic performance of two representative Zr-containing intermetallic systems, namely Cu-Zr and Pd-Zr, have been comparatively studied operando using methanol steam reforming (MSR) as test reaction. Using an inverse surface science and bulk model catalyst approach, we monitored the transition of the initial metal/intermetallic compound structures into the eventual active an...