Abstract:Nanostructured titania was synthesized by colloidal and polymeric sol-gel routes. Stable colloidal and polymeric titania sols were prepared by adjusting the proper values of the acid/alkoxide and the water/alkoxide molar ratios. The properties of sols were determined by dynamic light scattering technique and synthesized titania was characterized by thermogravimetry and differential the...

In this paper we report on the gravity-driven transport of rigid spheres of various sizes through the fluid–fluid interface of a demixed colloid–polymer mixture. Three consecutive stages can be distinguished: (i) the sphere approaches the interface by sedimenting through the polymer-rich phase, (ii) it is subsequently transported to the colloid-rich phase and (iii) it moves away from the interf...

whey contains more than half of total solids present in the original milk, which includes 20% of the proteins, most of the lactose, minerals and water soluble vitamins. in this study, selective separation of whey components by aphron flotation (separation of ultrafine particles by micro-bubbles) has been investigated. it has been shown that it is possible to recover valuable components of whey ...

Water purification technologies such as microfiltration/ultrafiltration and reverse osmosis utilize porous membranes to remove suspended particles and solutes. These membranes, however, cause many drawbacks such as a high pumping cost and a need for periodic replacement due to fouling. Here we show an alternative membraneless method for separating suspended particles by exposing the colloidal s...

Electrostatic correlations play an important role in physics, chemistry and biology. In plasmas they result in thermodynamic instability similar to the liquid-gas phase transition of simple molecular fluids. For charged colloidal suspensions the electrostatic correlations are responsible for screening and colloidal charge renormalization. In aqueous solutions containing multivalent counterions ...

Whey contains more than half of total solids present in the original milk, which includes 20% of the proteins, most of the lactose, minerals and water soluble vitamins. In this study, selective separation of whey components by Aphron flotation (separation of ultrafine particles by micro-bubbles) has been investigated. It has been shown that it is possible to recover valuable components of w...

Colloidal synthesis routes have been recently used to fabricate heterogeneous catalysts with more controllable and homogeneous properties. Herein a method was developed to modify the surface composition of colloidal nanocrystal catalysts and to purposely introduce specific atoms via ligands and change the catalyst reactivity. Organic ligands adsorbed on the surface of iron oxide catalysts were ...

Nanoparticle-ligand systems can be targeted to specific analytes to effect a change in the properties of the nanoparticles. We will examine two examples in which the electromagnetic properties of the nanoparticles (arising from their small size) are altered by analyte binding, and can be applied as a transducer in a chemical sensing system for explosive analytes. The first property reviewed is ...

The synthesis of highly-crystalline porous TiO(2) microspheres is reported using ultrasonic spray pyrolysis (USP) in the presence of colloidal silica as a template. We have exploited the interactions between hot SiO(2) template particles surface and TiO(2) precursor that occur during reaction inside the droplets, to control the physical and chemical properties of the resulting particles. Varyin...

An extension of the Asakura-Oosawa-Vrij model of hard sphere colloids and nonadsorbing polymers is studied with grand canonical Monte Carlo simulations and density functional theory. Polymer nonideality is taken into account through a repulsive step-function pair potential between polymers. Simulation results validate previous theoretical findings for the shift of the bulk fluid demixing binoda...