The recent availability of shale gas has led to a renewed interest in C-H bond activation as the first step towards the synthesis of fuels and fine chemicals. Heterogeneous catalysts based on Ni and Pt can perform this chemistry, but deactivate easily due to coke formation. Cu-based catalysts are not practical due to high C-H activation barriers, but their weaker binding to adsorbates offers re...

We selected, as the objects of our research, lignite from the Beizao Mine, gas coal from the Caiyuan Mine, coking coal from the Xiqu Mine, and anthracite from the Guhanshan Mine. We used the mercury intrusion method and the low-temperature liquid nitrogen adsorption method to analyze the structure and shape of the coal pores and calculated the fractal dimensions of different aperture segments i...

Catalytic biomass conversion is often hindered by coking. Carbon compounds cover active surface and plug pores, causing catalyst deactivation. Material design at the nanoscale allows tailoring of the catalytic activity and stability. Here, we report a simple synthesis of nanosized ZSM-5 materials by using a silicalite-1 seeding suspension. ZSM-5 crystals were grown from a deionized silica sourc...

The danger excessive coking pressure poses to the integrity and longevity of coke ovens has been recognized for many years [1-7]. During carbonisation in a coke oven fissures in the coke are generated due to stresses that arise from the differential contraction rates in adjacent layers of coke, which are at different temperatures [8]. Typically they are longitudinal, i.e. perpendicular to the o...

Indole is widely spread in various environmental matrices. Indole degradation by bacteria has been reported previously, whereas its degradation processes driven by aerobic microbial community were as-yet unexplored. Herein, eight sequencing batch bioreactors fed with municipal and coking activated sludges were constructed for aerobic treatment of indole. The whole operation processes contained ...

Ñ Anticoking Coatings for High Temperature Petrochemical Reactors Ñ Coke deposition is a major problem for several refinery and petrochemical processes, among which steam cracking for ethylene production. Decreasing coking rates will reduce decoking frequency and will also decrease heat transfer degradation. For these processes, a means of reducing coking phenomena is the application of anticok...

The supplementary data have included a full range of TEM pictures of the post-run samples, including 400 oC calcinated MoO3/H-ZSM-5 samples (coked) and the parent H-ZSM-5 (coked), showing the distribution of Mo clusters on the zeolite crystallite external surface, and the observed coke deposition upon the spreading of the Mo species. The Figures S1-S9 are the complementary of the Fig. 8 in the ...

Technological objects and processes are often characterized by fuzzy initial information necessary for developing their models optimization. The purpose of the study is to develop a method synthesizing linguistic described heuristic solving multicriteria optimization problem in environment. Based on expert assessments logical rules conditional inference, was developed describing with input outp...

Hydrogen produced from renewable energy sources can present significant environmental benefits as an alternative to fossil fuels or as a means for clean power generation via fuel cells. The aqueous fraction of bio oil can be used as a source for hydrogen production, if reformed in the presence of active catalytic materials. Recently, we introduced the concept of the spouted bed reactor for the ...