The complexes of Fe(II), Mn(II) and Ni(II) with a combination of a Schiff base, nitrogen-donor ligand or macrocyclic ligand and trithiocyanuric acid (ttcH3) were prepared and characterized by elemental analysis and spectroscopies. Crystal and molecular structures of the iron complex of composition [Fe(L1)](ttcH2)(ClO4)·EtOH·H2O (1), where L1 is Schiff base derived from tris(2-aminoethyl)amine a...

The crystal structure of the title Schiff base complex is obtained by single-crystal X-ray diffraction data.The solid state structure determination reveals that the coordination geometry around the copper(II) center istetrahedrally distorted square-planar. The crystal packing shows one dimensional infinite chains which arisesfrom the intermolecular interaction and stabilize the crystal packing.

Metal complexes of Cu (II), Co (II), Ni (II) and Zn (II) of Schiff based derived from 5-bromo-2hydroxybenzaldehyde and 4-nitobenzenesulfonamide have been prepared and characterized on the basis of physical characteristics, micro-analytical data, H NMR, FTIR spectrum and electronic data. The spectrum data 1 exhibit coordination of Schiff base with metal through imine nitrogen and oxygen atom and...

A component of the shikimate biosynthetic pathway, dehydroquinate dehydratase (DHQD) catalyzes the dehydration of 3-dehydroquniate (DHQ) to 3-dehydroshikimate. In the type I DHQD reaction mechanism a lysine forms a Schiff base intermediate with DHQ. The Schiff base acts as an electron sink to facilitate the catalytic dehydration. To address the mechanism of Schiff base formation, we determined ...

in this paper, plate-like nio nanoparticles were prepared by one-pot solid-state thermal decomposition of nickel (ii) schiff base complex as new precursor. first, the nickel (ii) schiff base precursor was prepared by solid-state grinding using nickel (ii) nitrate hexahydrate, ni(no3)2∙6h2o, and the schiff base ligand n,n′-bis-(salicylidene) benzene-1,4-diamine) for 30 min without using any solv...

This study reports the synthesis of chitosan anchored Schiff base, ([2-oxo-1H-indol-3-ylidene] amino) chitosan and its Cu (II) metal complex. The complex was characterized by elemental analysis, FT-IR Spectrum, thermogravimetry analysis .The crystallinity of the compound was analyzed by powder X-ray diffraction technique. The catalytic efficiency of complex was studied in the oxidation of alcoh...

This study reports the synthesis of chitosan anchored Schiff base, ([2-oxo-1H-indol-3-ylidene] amino) chitosan and its Cu (II) metal complex. The complex was characterized by elemental analysis, FT-IR Spectrum, thermogravimetry analysis .The crystallinity of the compound was analyzed by powder X-ray diffraction technique. The catalytic efficiency of complex was studied in the oxidation of alcoh...

In this paper, we report the synthesis and characterization of a new symmetric macroacyclic Schiff base ligand (H2L) and related complexes with different metals. (H2L) was synthesized by the one pot condensation reaction of 2-[2-(2-formyl phenoxy)ethoxy]benzaldehyde and 2-aminobenzenethiol in a 1:2 molar ratio. The acyclic Schiff base was characterized by IR, NMR spectroscopy and elemental anal...

Copper(II) complexes of a novel pyrazole containing porphyrinogen and cobalt(III) and zinc(II) complexes of a pyrazole containing tripodal ligand having N-donor atoms have been investigated. 5-Methyl-3-formylpyrazole (MPA) on reaction with copper(II) nitrate or perchlorate in the presence of tris(2-aminoethyl)amine (tren) forms novel pyrazole-based porphyrinogen complexes [Cu(T(3)-porphyrinogen...

One of the best and the most active ways for surveying thermal behaviour of materials is using differential scanning calorimetry. In this paper, the authors have studied thermal behaviour for Schiff base ligand and their synthesized Cobalt, Nickel complexes. In this method, the sample is opposed to a controlled temperature change and its physical properties. Here we studied melting point and Tg...