نتایج جستجو برای: charge transfer complex

تعداد نتایج: 1166147  

Journal: :Physical chemistry chemical physics : PCCP 2010
Olga D Parashchuk Vladimir V Bruevich Dmitry Yu Paraschuk

The donor-acceptor ground-state charge-transfer complex (CTC) formed in solution between a conjugated polymer, poly[methoxy-5-(2'-ethylhexyloxy)-1,4-phenylene-vinylene] (MEH-PPV), and a low-molecular-weight organic acceptor, 2,4,7-trinitrofluorenone (TNF), is studied by optical absorption and Raman spectroscopy. The CTC absorption as a function of TNF content shows a threshold increase that is ...

Journal: :Chemical communications 2002
Jae Wook Lee Kyungpil Kim SooWhan Choi Young Ho Ko Shigeru Sakamoto Kentaro Yamaguchi Kimoon Kim

For the first time, host-induced intramolecular charge-transfer complex formation in a guest containing both an electron donor and an electron acceptor is demonstrated in the cucurbit[8]uril cavity, leading to unusual back-folding of the guest molecule.

2005
O. Bénichou J. Klafter M. Moreau G. Oshanin

We present a microscopic model of a charge carrier transfer under an action of a constant electric field in a complex medium. Generalizing previous theoretical approaches, we model the dynamical environment hindering the carrier motion by dynamic perco-lation, i.e., as a medium comprising particles which move randomly on a simple cubic lattice, constrained by hard-core exclusion, and may sponta...

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