ZSM-5 zeolite is an aluminosilicate that usually has a high silica-to-alumina ratio. It contains two sets of nanopores. One set of nanopores is straight, with the cross-sectional size of 5.3 5.6 Å; the other set is Sshaped, with the cross-sectional size of 5.2 5.5 Å. An A1 atom at the center of an AlO4 tetrahedron connects to adjacent SiO4 tetrahedron by sharing an O atom and thus generates a n...

Fe2O3/ZSM-5 modified with Ce via citrate route (sol-gel approach) is applied for H2S removal in 500–700 ◦C temperature range. The sulfidation activity of Fe2O3/ZSM-5 is appreciably promoted by introduction of Ce plausibly attributed to the synergy of Fe2O3 and CeO2. 5Fe5Ce/ZSM-5 performs the optimal desulfurization behavior at 600 ◦C with sulfur capacity of 1020 μmol S/g, and the sulfidation pr...

mfi-type zeolite membranes (zsm-5) were prepared on α-alumina tubular supports and tested for separation of h2/co mixtures. the effect of pressure and temperature on h2 and co flows and selectivity was investigated. the best results in this work were obtained with a zsm-5 membrane prepared over a porous α-alumina tube seeded with zeolite nanocrystals synthesized with microwave technique. in thi...

The most studied catalysts for methane dehydroaromatization (MDA)?Mo/ZSM-5?are not commercialized yet due to the rapid deactivation and insufficient activity. Catalytic systems based on Fe Re are potential alternatives Mo-containing zeolites. Here, we compare catalytic performance of these as a function metal type its loading in ZSM-5 zeolite. results show that activity decreases order Re/ZSM-5...

The precise pore sizes defined by crystalline zeolite lattices have led to intensive research on zeolite membranes. Unfortunately, zeolites have been extremely difficult to prepare in a defect-free thin film form needed for membrane flux and selectivity. We introduced tetrapropylammonium (TPA), a structure-directing agent for zeolite ZSM-5, into a silica sol and exploit the development of high ...

Zeolites are promising materials in the field of gas sensors. In this technology-oriented paper, a planar setup for potentiometric hydrocarbon and hydrogen gas sensors using zeolites as ionic sodium conductors is presented, in which the Pt-loaded Na-ZSM-5 zeolite is applied using a thick-film technique between two interdigitated gold electrodes and one of them is selectively covered for the fir...

The catalytic conversion of palm oil was carried out over four zeolite catalysts—Y, ZSM-5, Y-ZSM-5 hybrid, and Y/ZSM-5 composite—to produce jet biofuel with high amount alkanes low aromatic hydrocarbons. hybrid catalyst synthesized using crystalline Y as the seed for growth ZSM-5. Synthesized catalysts were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, field-emiss...

The structure of phenylcyclopropane radical cation (1•+, R ) H) is derived from CIDNP effects observed during the electron transfer reaction of 1 with chloranil. This species is an example of an elusive structure type. The secondary cyclopropane protons show significantly divergent hyperfine coupling constants due to an unprecedented stereoelectronic effect. Incorporation into a redox-active pe...